Measurements of motionally averaged heteronuclear dipolar couplings in MAS NMR using R-type recoupling

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Measurements of motionally averaged heteronuclear dipolar couplings in MAS NMR using R-type recoupling. / Dvinskikh, Sergey V.; Zimmermann, Herbert; Maliniak, Arnold; Sandström, Dick.

In: Journal of Magnetic Resonance, Vol. 168, No. 2, 01.06.2004, p. 194-201.

Research output: Contribution to journal › Article › peer-review

Author

Dvinskikh, Sergey V. ; Zimmermann, Herbert ; Maliniak, Arnold ; Sandström, Dick. / Measurements of motionally averaged heteronuclear dipolar couplings in MAS NMR using R-type recoupling. In: Journal of Magnetic Resonance. 2004 ; Vol. 168, No. 2. pp. 194-201.

BibTeX

@article{3619e58b14554a23b28634b851cf4c86,

title = "Measurements of motionally averaged heteronuclear dipolar couplings in MAS NMR using R-type recoupling",

abstract = "A novel MAS NMR approach is presented for the determination of heteronuclear dipolar couplings in unoriented materials. The technique is based on the proton-detected local field (PDLF) protocol, and achieves dipolar recoupling by R-type radio-frequency irradiation. The experiment, which is called R-PDLF spectroscopy, is demonstrated on solid and liquid-crystalline systems. For mobile systems, it is shown that the R-PDLF scheme provides better dipolar resolution as compared to techniques combining conventional separated local field (SLF) spectroscopy with R-type recoupling.",

keywords = "Heteronuclear recoupling, Magic-angle spinning, PDLF, R-type sequences, SLF",

author = "Dvinskikh, {Sergey V.} and Herbert Zimmermann and Arnold Maliniak and Dick Sandstr{\"o}m",

year = "2004",

month = jun,

day = "1",

doi = "10.1016/j.jmr.2004.03.001",

language = "English",

volume = "168",

pages = "194--201",

journal = "Journal of Magnetic Resonance - Series A",

issn = "1090-7807",

publisher = "Elsevier",

number = "2",

}

RIS

TY - JOUR

T1 - Measurements of motionally averaged heteronuclear dipolar couplings in MAS NMR using R-type recoupling

AU - Dvinskikh, Sergey V.

AU - Zimmermann, Herbert

AU - Maliniak, Arnold

AU - Sandström, Dick

PY - 2004/6/1

Y1 - 2004/6/1

N2 - A novel MAS NMR approach is presented for the determination of heteronuclear dipolar couplings in unoriented materials. The technique is based on the proton-detected local field (PDLF) protocol, and achieves dipolar recoupling by R-type radio-frequency irradiation. The experiment, which is called R-PDLF spectroscopy, is demonstrated on solid and liquid-crystalline systems. For mobile systems, it is shown that the R-PDLF scheme provides better dipolar resolution as compared to techniques combining conventional separated local field (SLF) spectroscopy with R-type recoupling.

AB - A novel MAS NMR approach is presented for the determination of heteronuclear dipolar couplings in unoriented materials. The technique is based on the proton-detected local field (PDLF) protocol, and achieves dipolar recoupling by R-type radio-frequency irradiation. The experiment, which is called R-PDLF spectroscopy, is demonstrated on solid and liquid-crystalline systems. For mobile systems, it is shown that the R-PDLF scheme provides better dipolar resolution as compared to techniques combining conventional separated local field (SLF) spectroscopy with R-type recoupling.

KW - Heteronuclear recoupling

KW - Magic-angle spinning

KW - PDLF

KW - R-type sequences

KW - SLF

UR - http://www.scopus.com/inward/record.url?scp=2342527174&partnerID=8YFLogxK

U2 - 10.1016/j.jmr.2004.03.001

DO - 10.1016/j.jmr.2004.03.001

M3 - Article

C2 - 15140427

AN - SCOPUS:2342527174

VL - 168

SP - 194

EP - 201

JO - Journal of Magnetic Resonance - Series A

JF - Journal of Magnetic Resonance - Series A

SN - 1090-7807

IS - 2

ER -

ID: 48948559