A novel MAS NMR approach is presented for the determination of heteronuclear dipolar couplings in unoriented materials. The technique is based on the proton-detected local field (PDLF) protocol, and achieves dipolar recoupling by R-type radio-frequency irradiation. The experiment, which is called R-PDLF spectroscopy, is demonstrated on solid and liquid-crystalline systems. For mobile systems, it is shown that the R-PDLF scheme provides better dipolar resolution as compared to techniques combining conventional separated local field (SLF) spectroscopy with R-type recoupling.

Original languageEnglish
Pages (from-to)194-201
Number of pages8
JournalJournal of Magnetic Resonance
Volume168
Issue number2
DOIs
StatePublished - 1 Jun 2004

    Scopus subject areas

  • Biophysics
  • Biochemistry
  • Nuclear and High Energy Physics
  • Condensed Matter Physics

    Research areas

  • Heteronuclear recoupling, Magic-angle spinning, PDLF, R-type sequences, SLF

ID: 48948559