Research output: Contribution to journal › Article › peer-review
A novel MAS NMR approach is presented for the determination of heteronuclear dipolar couplings in unoriented materials. The technique is based on the proton-detected local field (PDLF) protocol, and achieves dipolar recoupling by R-type radio-frequency irradiation. The experiment, which is called R-PDLF spectroscopy, is demonstrated on solid and liquid-crystalline systems. For mobile systems, it is shown that the R-PDLF scheme provides better dipolar resolution as compared to techniques combining conventional separated local field (SLF) spectroscopy with R-type recoupling.
| Original language | English |
|---|---|
| Pages (from-to) | 194-201 |
| Number of pages | 8 |
| Journal | Journal of Magnetic Resonance |
| Volume | 168 |
| Issue number | 2 |
| DOIs | |
| State | Published - 1 Jun 2004 |
ID: 48948559