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@article{a68ff82966a243efaae70691e5fa1fb1,
title = "Ionophore-Based Ion-Selective Electrodes in Non-Zero Current Modes:: Mechanistic Studies and the Possibilities of the Analytical Application",
abstract = "Abstract: This mini review briefly describes (i) literature data on the non-zero current measurements with ionophore-based ion-selective electrodes (ISEs) aimed at fundamental studies of the mechanism of their potentiometric response, and (ii) the data on the possibilities of analytical applications of ISEs in voltametric and constant potential chronoamperometric/coulometric modes, in particular the K + ion assay in blood serum with the sensitivity of 0.1%. A special attention is paid to the basics of voltammetry and chronoamperometry/coulometry with the ionophore-based ISEs, and to how and why these methods differ from the classical voltammetry and coulometry. ",
keywords = "chronopotentiometry, constant potential chronoamperometry/coulometry, impedance, ion-selective electrodes, ionophores, voltammetry",
author = "Бондарь, {Анна Владимировна} and Керестень, {Валентина Максимовна} and Михельсон, {Константин Николаевич}",
note = "Publisher Copyright: {\textcopyright} 2022, The Author(s).",
year = "2022",
month = feb,
doi = "10.1134/S1061934822020046",
language = "English",
volume = "77",
pages = "145--154",
journal = "Journal of Analytical Chemistry",
issn = "1061-9348",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - Ionophore-Based Ion-Selective Electrodes in Non-Zero Current Modes:

T2 - Mechanistic Studies and the Possibilities of the Analytical Application

AU - Бондарь, Анна Владимировна

AU - Керестень, Валентина Максимовна

AU - Михельсон, Константин Николаевич

N1 - Publisher Copyright: © 2022, The Author(s).

PY - 2022/2

Y1 - 2022/2

N2 - Abstract: This mini review briefly describes (i) literature data on the non-zero current measurements with ionophore-based ion-selective electrodes (ISEs) aimed at fundamental studies of the mechanism of their potentiometric response, and (ii) the data on the possibilities of analytical applications of ISEs in voltametric and constant potential chronoamperometric/coulometric modes, in particular the K + ion assay in blood serum with the sensitivity of 0.1%. A special attention is paid to the basics of voltammetry and chronoamperometry/coulometry with the ionophore-based ISEs, and to how and why these methods differ from the classical voltammetry and coulometry.

AB - Abstract: This mini review briefly describes (i) literature data on the non-zero current measurements with ionophore-based ion-selective electrodes (ISEs) aimed at fundamental studies of the mechanism of their potentiometric response, and (ii) the data on the possibilities of analytical applications of ISEs in voltametric and constant potential chronoamperometric/coulometric modes, in particular the K + ion assay in blood serum with the sensitivity of 0.1%. A special attention is paid to the basics of voltammetry and chronoamperometry/coulometry with the ionophore-based ISEs, and to how and why these methods differ from the classical voltammetry and coulometry.

KW - chronopotentiometry

KW - constant potential chronoamperometry/coulometry

KW - impedance

KW - ion-selective electrodes

KW - ionophores

KW - voltammetry

UR - http://www.scopus.com/inward/record.url?scp=85126102783&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/33c44683-e3c1-3239-b0df-40304318235f/

U2 - 10.1134/S1061934822020046

DO - 10.1134/S1061934822020046

M3 - Review article

VL - 77

SP - 145

EP - 154

JO - Journal of Analytical Chemistry

JF - Journal of Analytical Chemistry

SN - 1061-9348

IS - 2

ER -

ID: 100274476