The successive ionization potentials (IPs) and electron affinities (EAs) for superheavy elements with 111≤Z≤114, namely, Rg, Cn, Nh, and Fl, are reexamined using the relativistic Fock-space coupled-cluster method with nonperturbative single (S), double (D), and triple (T) cluster amplitudes (FS-CCSDT). For most of the considered quantities, the triple-amplitude contributions turn out to be important. The Breit and frequency-dependent Breit corrections are evaluated by means of the configuration-interaction method. The quantum-electrodynamics corrections to the IPs and EAs are taken into account within the model-QED-operator approach. The obtained results are within 0.10 eV uncertainty.

Original languageEnglish
Article number062805
Pages (from-to)062805
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume105
Issue number6
DOIs
StatePublished - 8 Jun 2022

    Scopus subject areas

  • Atomic and Molecular Physics, and Optics

ID: 95736180