Research output: Contribution to journal › Article › peer-review
Impurity absorption and luminescence of CuGaSe2 crystals. / Ponomareva, I. A.; Serov, A. Yu; Bodnar', I. V.
In: Physics of the Solid State, Vol. 49, No. 1, 01.01.2007, p. 23-27.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Impurity absorption and luminescence of CuGaSe2 crystals
AU - Ponomareva, I. A.
AU - Serov, A. Yu
AU - Bodnar', I. V.
PY - 2007/1/1
Y1 - 2007/1/1
N2 - A comparison of the experimental and calculated absorption spectra of CuGaSe2 crystals revealed the existence of two acceptor levels with ionization energies of 66 and 167 meV in the samples under study. It was found that the luminescence spectra of CuGaSe2 measured at 77 K exhibit four impurity-band transitions with impurity ionization energies of 66, 99, 136, and 190 meV. An analysis of the temperature dependence of the luminescence intensity in the temperature range 11-77 K revealed a band peaking at 1.671 eV due to the radiation of donor-acceptor pairs. The calculated sum of the ionization energies of the impurities responsible for the formation of donor-acceptor pairs and the temperature dependence of the relative intensities of impurity-band emission were used to determine the ionization energies of the corresponding donor and acceptor.
AB - A comparison of the experimental and calculated absorption spectra of CuGaSe2 crystals revealed the existence of two acceptor levels with ionization energies of 66 and 167 meV in the samples under study. It was found that the luminescence spectra of CuGaSe2 measured at 77 K exhibit four impurity-band transitions with impurity ionization energies of 66, 99, 136, and 190 meV. An analysis of the temperature dependence of the luminescence intensity in the temperature range 11-77 K revealed a band peaking at 1.671 eV due to the radiation of donor-acceptor pairs. The calculated sum of the ionization energies of the impurities responsible for the formation of donor-acceptor pairs and the temperature dependence of the relative intensities of impurity-band emission were used to determine the ionization energies of the corresponding donor and acceptor.
UR - http://www.scopus.com/inward/record.url?scp=33846240866&partnerID=8YFLogxK
U2 - 10.1134/S1063783407010052
DO - 10.1134/S1063783407010052
M3 - Article
AN - SCOPUS:33846240866
VL - 49
SP - 23
EP - 27
JO - Physics of the Solid State
JF - Physics of the Solid State
SN - 1063-7834
IS - 1
ER -
ID: 36170656