Standard

Impact of counterions on micelle formation and polymerization of 11-acryloyloxyundecyltrimethylammonium surfactants. / Fetin, P. A.; Zorin, I. M.; Lezov, A. A.; Fetina, V. I.; Bilibin, A. Yu.

In: Journal of Molecular Liquids, Vol. 309, 113103, 01.07.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Fetin, PA, Zorin, IM, Lezov, AA, Fetina, VI & Bilibin, AY 2020, 'Impact of counterions on micelle formation and polymerization of 11-acryloyloxyundecyltrimethylammonium surfactants', Journal of Molecular Liquids, vol. 309, 113103. https://doi.org/10.1016/j.molliq.2020.113103

APA

Fetin, P. A., Zorin, I. M., Lezov, A. A., Fetina, V. I., & Bilibin, A. Y. (2020). Impact of counterions on micelle formation and polymerization of 11-acryloyloxyundecyltrimethylammonium surfactants. Journal of Molecular Liquids, 309, [113103]. https://doi.org/10.1016/j.molliq.2020.113103

Vancouver

Fetin PA, Zorin IM, Lezov AA, Fetina VI, Bilibin AY. Impact of counterions on micelle formation and polymerization of 11-acryloyloxyundecyltrimethylammonium surfactants. Journal of Molecular Liquids. 2020 Jul 1;309. 113103. https://doi.org/10.1016/j.molliq.2020.113103

Author

Fetin, P. A. ; Zorin, I. M. ; Lezov, A. A. ; Fetina, V. I. ; Bilibin, A. Yu. / Impact of counterions on micelle formation and polymerization of 11-acryloyloxyundecyltrimethylammonium surfactants. In: Journal of Molecular Liquids. 2020 ; Vol. 309.

BibTeX

@article{6d4487e2000642df9df7ec1b2bda0497,
title = "Impact of counterions on micelle formation and polymerization of 11-acryloyloxyundecyltrimethylammonium surfactants",
abstract = "New surfactants based on the cationic monomer 11-acryloyloxyundecyltrimethylammonium with counterions bromide, nitrate, acetate, camphorsulfonate, 4-toluenesulfonate, trifluoroacetate were obtained in this work. In most cases counterions change the critical micelle concentration by 2–3 times (being compared with bromide) except sample with acetate counterions (in this case critical micelle concentration increases by an order of magnitude). Substitution of bromide for hydrophobic counterions (toluenesulfonate, trifluoroacetate, camphorsulfonate) does not lead to expected transformation of spherical micelles to long wormlike micelles. The polymerization of such monomers occurs according to the microemulsion mechanism involving micelles of monomers.",
keywords = "Comb-like polyelectrolytes, Surface-active monomers, Surfactant polymerization, Wormlike micelles, COMPLEX, MONOMERS, KINETICS",
author = "Fetin, {P. A.} and Zorin, {I. M.} and Lezov, {A. A.} and Fetina, {V. I.} and Bilibin, {A. Yu}",
year = "2020",
month = jul,
day = "1",
doi = "10.1016/j.molliq.2020.113103",
language = "English",
volume = "309",
journal = "Journal of Molecular Liquids",
issn = "0167-7322",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Impact of counterions on micelle formation and polymerization of 11-acryloyloxyundecyltrimethylammonium surfactants

AU - Fetin, P. A.

AU - Zorin, I. M.

AU - Lezov, A. A.

AU - Fetina, V. I.

AU - Bilibin, A. Yu

PY - 2020/7/1

Y1 - 2020/7/1

N2 - New surfactants based on the cationic monomer 11-acryloyloxyundecyltrimethylammonium with counterions bromide, nitrate, acetate, camphorsulfonate, 4-toluenesulfonate, trifluoroacetate were obtained in this work. In most cases counterions change the critical micelle concentration by 2–3 times (being compared with bromide) except sample with acetate counterions (in this case critical micelle concentration increases by an order of magnitude). Substitution of bromide for hydrophobic counterions (toluenesulfonate, trifluoroacetate, camphorsulfonate) does not lead to expected transformation of spherical micelles to long wormlike micelles. The polymerization of such monomers occurs according to the microemulsion mechanism involving micelles of monomers.

AB - New surfactants based on the cationic monomer 11-acryloyloxyundecyltrimethylammonium with counterions bromide, nitrate, acetate, camphorsulfonate, 4-toluenesulfonate, trifluoroacetate were obtained in this work. In most cases counterions change the critical micelle concentration by 2–3 times (being compared with bromide) except sample with acetate counterions (in this case critical micelle concentration increases by an order of magnitude). Substitution of bromide for hydrophobic counterions (toluenesulfonate, trifluoroacetate, camphorsulfonate) does not lead to expected transformation of spherical micelles to long wormlike micelles. The polymerization of such monomers occurs according to the microemulsion mechanism involving micelles of monomers.

KW - Comb-like polyelectrolytes

KW - Surface-active monomers

KW - Surfactant polymerization

KW - Wormlike micelles

KW - COMPLEX

KW - MONOMERS

KW - KINETICS

UR - http://www.scopus.com/inward/record.url?scp=85083325131&partnerID=8YFLogxK

U2 - 10.1016/j.molliq.2020.113103

DO - 10.1016/j.molliq.2020.113103

M3 - Article

AN - SCOPUS:85083325131

VL - 309

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

SN - 0167-7322

M1 - 113103

ER -

ID: 61283873