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Hyperfine structure in thallium atom : Study of nuclear magnetization distribution effects. / Prosnyak, S. D.; Maison, D. E.; Skripnikov, L. V.

In: Journal of Chemical Physics, Vol. 152, No. 4, 044301, 31.01.2020.

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@article{19c604a3c0d44f84955314512cca660c,
title = "Hyperfine structure in thallium atom: Study of nuclear magnetization distribution effects",
abstract = "The influence of the nuclear magnetization distribution effects on the hyperfine structure of electronic states of thallium atom is studied within the relativistic coupled cluster theory. Relative significance of these effects is demonstrated for the first excited electronic state 6P3/2 of neutral Tl. Based on the obtained theoretical and available experimental data, the nuclear magnetic moments of short-lived 191Tlm and 193Tlm isotopes are predicted: μ191 = 3.79(2) μN and μ193 = 3.84(3) μN, respectively. Using theoretical and experimental data for the neutral Tl, the magnetic anomalies 205Δ203 for the 7S1/2 state of the neutral Tl atom and the 1S1/2 state of the hydrogen-like ion are also predicted.",
keywords = "ELECTRONIC STATES, excited states, Magnetic moments, magnetization, Numerical methods, Thallium, ANOMALIES, STATE, DIPOLE, TABLE, HFS SEPARATIONS, TL-203, 5P, 4P, ZETA BASIS-SETS",
author = "Prosnyak, {S. D.} and Maison, {D. E.} and Skripnikov, {L. V.}",
year = "2020",
month = jan,
day = "31",
doi = "10.1063/1.5141090",
language = "English",
volume = "152",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics",
number = "4",

}

RIS

TY - JOUR

T1 - Hyperfine structure in thallium atom

T2 - Study of nuclear magnetization distribution effects

AU - Prosnyak, S. D.

AU - Maison, D. E.

AU - Skripnikov, L. V.

PY - 2020/1/31

Y1 - 2020/1/31

N2 - The influence of the nuclear magnetization distribution effects on the hyperfine structure of electronic states of thallium atom is studied within the relativistic coupled cluster theory. Relative significance of these effects is demonstrated for the first excited electronic state 6P3/2 of neutral Tl. Based on the obtained theoretical and available experimental data, the nuclear magnetic moments of short-lived 191Tlm and 193Tlm isotopes are predicted: μ191 = 3.79(2) μN and μ193 = 3.84(3) μN, respectively. Using theoretical and experimental data for the neutral Tl, the magnetic anomalies 205Δ203 for the 7S1/2 state of the neutral Tl atom and the 1S1/2 state of the hydrogen-like ion are also predicted.

AB - The influence of the nuclear magnetization distribution effects on the hyperfine structure of electronic states of thallium atom is studied within the relativistic coupled cluster theory. Relative significance of these effects is demonstrated for the first excited electronic state 6P3/2 of neutral Tl. Based on the obtained theoretical and available experimental data, the nuclear magnetic moments of short-lived 191Tlm and 193Tlm isotopes are predicted: μ191 = 3.79(2) μN and μ193 = 3.84(3) μN, respectively. Using theoretical and experimental data for the neutral Tl, the magnetic anomalies 205Δ203 for the 7S1/2 state of the neutral Tl atom and the 1S1/2 state of the hydrogen-like ion are also predicted.

KW - ELECTRONIC STATES

KW - excited states

KW - Magnetic moments

KW - magnetization

KW - Numerical methods

KW - Thallium

KW - ANOMALIES

KW - STATE

KW - DIPOLE

KW - TABLE

KW - HFS SEPARATIONS

KW - TL-203

KW - 5P

KW - 4P

KW - ZETA BASIS-SETS

UR - http://www.scopus.com/inward/record.url?scp=85078447303&partnerID=8YFLogxK

U2 - 10.1063/1.5141090

DO - 10.1063/1.5141090

M3 - Article

AN - SCOPUS:85078447303

VL - 152

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 4

M1 - 044301

ER -

ID: 51270718