The influence of the nuclear magnetization distribution effects on the hyperfine structure of electronic states of thallium atom is studied within the relativistic coupled cluster theory. Relative significance of these effects is demonstrated for the first excited electronic state 6P3/2 of neutral Tl. Based on the obtained theoretical and available experimental data, the nuclear magnetic moments of short-lived 191Tlm and 193Tlm isotopes are predicted: μ191 = 3.79(2) μN and μ193 = 3.84(3) μN, respectively. Using theoretical and experimental data for the neutral Tl, the magnetic anomalies 205Δ203 for the 7S1/2 state of the neutral Tl atom and the 1S1/2 state of the hydrogen-like ion are also predicted.

Original languageEnglish
Article number044301
Number of pages8
JournalJournal of Chemical Physics
Volume152
Issue number4
Early online date22 Jan 2020
DOIs
StatePublished - 31 Jan 2020

    Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

    Research areas

  • ELECTRONIC STATES, excited states, Magnetic moments, magnetization, Numerical methods, Thallium, ANOMALIES, STATE, DIPOLE, TABLE, HFS SEPARATIONS, TL-203, 5P, 4P, ZETA BASIS-SETS

ID: 51270718