Halogen bonding between metal centers and halocarbons. / Ivanov, Daniil M.; Novikov, Alexander S.; Ananyev, Ivan V.; Kirina, Yulia V.; Kukushkin, Vadim Yu.
In: Chemical Communications, Vol. 52, No. 32, 2016.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Halogen bonding between metal centers and halocarbons
AU - Ivanov, Daniil M.
AU - Novikov, Alexander S.
AU - Ananyev, Ivan V.
AU - Kirina, Yulia V.
AU - Kukushkin, Vadim Yu.
PY - 2016
Y1 - 2016
N2 - Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk(2))(2)] (X = Cl, Br). The HI2C-I center dot center dot center dot eta(1)((Pt)) halogen bonding and the bifurcated HI2C-I center dot center dot center dot eta(2)((Pt-Cl)) halogen bonding - the latter undergoes the thermally induced reversible HI2C-I center dot center dot center dot eta(2)((Pt-Cl)) reversible arrow HI2C-I center dot center dot center dot eta(1)((Pt)) transformation - were observed and confirmed theoretically.
AB - Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk(2))(2)] (X = Cl, Br). The HI2C-I center dot center dot center dot eta(1)((Pt)) halogen bonding and the bifurcated HI2C-I center dot center dot center dot eta(2)((Pt-Cl)) halogen bonding - the latter undergoes the thermally induced reversible HI2C-I center dot center dot center dot eta(2)((Pt-Cl)) reversible arrow HI2C-I center dot center dot center dot eta(1)((Pt)) transformation - were observed and confirmed theoretically.
U2 - 10.1039/c6cc01107a
DO - 10.1039/c6cc01107a
M3 - Article
VL - 52
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 32
ER -
ID: 7927627