Standard

Formation of cyclo-E42- units (E4=P 4, As4, AsP3) by a Complex with a Cr-Cr Quintuple Bond. / Schwarzmaier, Christoph; Noor, Awal; Glatz, Germund; Zabel, Manfred; Timoshkin, Alexey Y.; Cossairt, Brandi M.; Cummins, Christopher C.; Kempe, Rhett; Scheer, Manfred.

In: Angewandte Chemie - International Edition, Vol. 50, No. 32, 01.08.2011, p. 7283-7286.

Research output: Contribution to journal › Article › peer-review

Harvard

Schwarzmaier, C, Noor, A, Glatz, G, Zabel, M, Timoshkin, AY, Cossairt, BM, Cummins, CC, Kempe, R & Scheer, M 2011, 'Formation of cyclo-E42- units (E4=P 4, As4, AsP3) by a Complex with a Cr-Cr Quintuple Bond', Angewandte Chemie - International Edition, vol. 50, no. 32, pp. 7283-7286. https://doi.org/10.1002/anie.201102361

APA

Schwarzmaier, C., Noor, A., Glatz, G., Zabel, M., Timoshkin, A. Y., Cossairt, B. M., Cummins, C. C., Kempe, R., & Scheer, M. (2011). Formation of cyclo-E42- units (E4=P 4, As4, AsP3) by a Complex with a Cr-Cr Quintuple Bond. Angewandte Chemie - International Edition, 50(32), 7283-7286. https://doi.org/10.1002/anie.201102361

Vancouver

Schwarzmaier C, Noor A, Glatz G, Zabel M, Timoshkin AY, Cossairt BM et al. Formation of cyclo-E42- units (E4=P 4, As4, AsP3) by a Complex with a Cr-Cr Quintuple Bond. Angewandte Chemie - International Edition. 2011 Aug 1;50(32):7283-7286. https://doi.org/10.1002/anie.201102361

Author

Schwarzmaier, Christoph ; Noor, Awal ; Glatz, Germund ; Zabel, Manfred ; Timoshkin, Alexey Y. ; Cossairt, Brandi M. ; Cummins, Christopher C. ; Kempe, Rhett ; Scheer, Manfred. / Formation of cyclo-E42- units (E4=P 4, As4, AsP3) by a Complex with a Cr-Cr Quintuple Bond. In: Angewandte Chemie - International Edition. 2011 ; Vol. 50, No. 32. pp. 7283-7286.

BibTeX

@article{571445bd2fb2470fbc64b2dda09ca587,
title = "Formation of cyclo-E42- units (E4=P 4, As4, AsP3) by a Complex with a Cr-Cr Quintuple Bond",
abstract = "White phosphorus, yellow arsenic, and AsP3 have been successfully activated by a complex with a Cr-Cr quintuple bond in one step leading to the formation of rare terminally bound cyclo-P4 2-, cyclo-As42-, and cyclo-AsP3 units. The subsequent reaction with an excess of [W(CO)5(thf)] leads to the coordination of one {W(CO)5} fragment in the thermodynamically most stable form according to DFT calculations.",
keywords = "arsenic, chromium, phosphorus, quintuple bonds",
author = "Christoph Schwarzmaier and Awal Noor and Germund Glatz and Manfred Zabel and Timoshkin, {Alexey Y.} and Cossairt, {Brandi M.} and Cummins, {Christopher C.} and Rhett Kempe and Manfred Scheer",
year = "2011",
month = aug,
day = "1",
doi = "10.1002/anie.201102361",
language = "English",
volume = "50",
pages = "7283--7286",
journal = "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION",
issn = "1433-7851",
publisher = "Wiley-Blackwell",
number = "32",

}

RIS

TY - JOUR

T1 - Formation of cyclo-E42- units (E4=P 4, As4, AsP3) by a Complex with a Cr-Cr Quintuple Bond

AU - Schwarzmaier, Christoph

AU - Noor, Awal

AU - Glatz, Germund

AU - Zabel, Manfred

AU - Timoshkin, Alexey Y.

AU - Cossairt, Brandi M.

AU - Cummins, Christopher C.

AU - Kempe, Rhett

AU - Scheer, Manfred

PY - 2011/8/1

Y1 - 2011/8/1

N2 - White phosphorus, yellow arsenic, and AsP3 have been successfully activated by a complex with a Cr-Cr quintuple bond in one step leading to the formation of rare terminally bound cyclo-P4 2-, cyclo-As42-, and cyclo-AsP3 units. The subsequent reaction with an excess of [W(CO)5(thf)] leads to the coordination of one {W(CO)5} fragment in the thermodynamically most stable form according to DFT calculations.

AB - White phosphorus, yellow arsenic, and AsP3 have been successfully activated by a complex with a Cr-Cr quintuple bond in one step leading to the formation of rare terminally bound cyclo-P4 2-, cyclo-As42-, and cyclo-AsP3 units. The subsequent reaction with an excess of [W(CO)5(thf)] leads to the coordination of one {W(CO)5} fragment in the thermodynamically most stable form according to DFT calculations.

KW - arsenic

KW - chromium

KW - phosphorus

KW - quintuple bonds

UR - http://www.scopus.com/inward/record.url?scp=79960896493&partnerID=8YFLogxK

U2 - 10.1002/anie.201102361

DO - 10.1002/anie.201102361

M3 - Article

AN - SCOPUS:79960896493

VL - 50

SP - 7283

EP - 7286

JO - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

JF - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SN - 1433-7851

IS - 32

ER -

ID: 36024695