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Entry to new spiroheterocycles via tandem Rh(II)-catalyzed O–H insertion/base-promoted cyclization involving diazoarylidene succinimides. / Янович, Александр Денисович; Вепрева, Анастасия Сергеевна; Малкова, Ксения Павловна; Кантин, Григорий Павлович; Дарьин, Дмитрий Викторович.

In: Beilstein Journal of Organic Chemistry, Vol. 20, 11.03.2024, p. 561–569.

Research output: Contribution to journal › Article › peer-review

Harvard

Янович, АД, Вепрева, АС, Малкова, КП, Кантин, ГП & Дарьин, ДВ 2024, 'Entry to new spiroheterocycles via tandem Rh(II)-catalyzed O–H insertion/base-promoted cyclization involving diazoarylidene succinimides', Beilstein Journal of Organic Chemistry, vol. 20, pp. 561–569. https://doi.org/10.3762/bjoc.20.48

APA

Янович, А. Д., Вепрева, А. С., Малкова, К. П., Кантин, Г. П., & Дарьин, Д. В. (2024). Entry to new spiroheterocycles via tandem Rh(II)-catalyzed O–H insertion/base-promoted cyclization involving diazoarylidene succinimides. Beilstein Journal of Organic Chemistry, 20, 561–569. https://doi.org/10.3762/bjoc.20.48

Vancouver

Янович АД, Вепрева АС, Малкова КП, Кантин ГП, Дарьин ДВ. Entry to new spiroheterocycles via tandem Rh(II)-catalyzed O–H insertion/base-promoted cyclization involving diazoarylidene succinimides. Beilstein Journal of Organic Chemistry. 2024 Mar 11;20:561–569. https://doi.org/10.3762/bjoc.20.48

Author

Янович, Александр Денисович ; Вепрева, Анастасия Сергеевна ; Малкова, Ксения Павловна ; Кантин, Григорий Павлович ; Дарьин, Дмитрий Викторович. / Entry to new spiroheterocycles via tandem Rh(II)-catalyzed O–H insertion/base-promoted cyclization involving diazoarylidene succinimides. In: Beilstein Journal of Organic Chemistry. 2024 ; Vol. 20. pp. 561–569.

BibTeX

@article{80b043493c0c47f1b350cc9f7ce942a1,
title = "Entry to new spiroheterocycles via tandem Rh(II)-catalyzed O–H insertion/base-promoted cyclization involving diazoarylidene succinimides",
abstract = "A facile approach to novel medicinally relevant spiro heterocyclic scaffolds (namely furan-2(5 H)-ones, tetrahydrofurans and pyrans spiro-conjugated with the succinimide ring) has been developed. The protocol consists of Rh(II)-catalyzed insertion of heterocyclic carbenes derived from diazoarylidene succinimides (DAS) into the O-H bond of propiolic/allenic acids or brominated alcohols, followed by base-promoted cyclization to afford the target spirocyclic compounds in good to high yields. ",
author = "Янович, {Александр Денисович} and Вепрева, {Анастасия Сергеевна} and Малкова, {Ксения Павловна} and Кантин, {Григорий Павлович} and Дарьин, {Дмитрий Викторович}",
year = "2024",
month = mar,
day = "11",
doi = "10.3762/bjoc.20.48",
language = "English",
volume = "20",
pages = "561–569",
journal = "Beilstein Journal of Organic Chemistry",
issn = "1860-5397",
publisher = "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften",

}

RIS

TY - JOUR

T1 - Entry to new spiroheterocycles via tandem Rh(II)-catalyzed O–H insertion/base-promoted cyclization involving diazoarylidene succinimides

AU - Янович, Александр Денисович

AU - Вепрева, Анастасия Сергеевна

AU - Малкова, Ксения Павловна

AU - Кантин, Григорий Павлович

AU - Дарьин, Дмитрий Викторович

PY - 2024/3/11

Y1 - 2024/3/11

N2 - A facile approach to novel medicinally relevant spiro heterocyclic scaffolds (namely furan-2(5 H)-ones, tetrahydrofurans and pyrans spiro-conjugated with the succinimide ring) has been developed. The protocol consists of Rh(II)-catalyzed insertion of heterocyclic carbenes derived from diazoarylidene succinimides (DAS) into the O-H bond of propiolic/allenic acids or brominated alcohols, followed by base-promoted cyclization to afford the target spirocyclic compounds in good to high yields.

AB - A facile approach to novel medicinally relevant spiro heterocyclic scaffolds (namely furan-2(5 H)-ones, tetrahydrofurans and pyrans spiro-conjugated with the succinimide ring) has been developed. The protocol consists of Rh(II)-catalyzed insertion of heterocyclic carbenes derived from diazoarylidene succinimides (DAS) into the O-H bond of propiolic/allenic acids or brominated alcohols, followed by base-promoted cyclization to afford the target spirocyclic compounds in good to high yields.

UR - https://www.mendeley.com/catalogue/ad38a8d7-9a71-338b-9047-9d5b0d7aacfe/

U2 - 10.3762/bjoc.20.48

DO - 10.3762/bjoc.20.48

M3 - Article

C2 - 38505240

VL - 20

SP - 561

EP - 569

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

SN - 1860-5397

ER -

ID: 117623629