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Efficient Suzuki-Miyaura mono-arylation of symmetrical diiodo(hetero)arenes. / Sapegin, Alexander; Krasavin, Mikhail.

In: Tetrahedron Letters, Vol. 59, No. 20, 16.05.2018, p. 1948-1951.

Research output: Contribution to journal › Article › peer-review

Harvard

Sapegin, A & Krasavin, M 2018, 'Efficient Suzuki-Miyaura mono-arylation of symmetrical diiodo(hetero)arenes', Tetrahedron Letters, vol. 59, no. 20, pp. 1948-1951. https://doi.org/10.1016/j.tetlet.2018.04.015

APA

Sapegin, A., & Krasavin, M. (2018). Efficient Suzuki-Miyaura mono-arylation of symmetrical diiodo(hetero)arenes. Tetrahedron Letters, 59(20), 1948-1951. https://doi.org/10.1016/j.tetlet.2018.04.015

Vancouver

Sapegin A, Krasavin M. Efficient Suzuki-Miyaura mono-arylation of symmetrical diiodo(hetero)arenes. Tetrahedron Letters. 2018 May 16;59(20):1948-1951. https://doi.org/10.1016/j.tetlet.2018.04.015

Author

Sapegin, Alexander ; Krasavin, Mikhail. / Efficient Suzuki-Miyaura mono-arylation of symmetrical diiodo(hetero)arenes. In: Tetrahedron Letters. 2018 ; Vol. 59, No. 20. pp. 1948-1951.

BibTeX

@article{4ddb0bb8a59d47839a742bcd388ee53c,
title = "Efficient Suzuki-Miyaura mono-arylation of symmetrical diiodo(hetero)arenes",
abstract = "A reliable protocol for converting 1,4-diiodo-2,3,5,6-tetrafluorobenzene into 1-(hetero)aryl-4-iodo-2,3,5,6-tetrafluorobenzene derivatives has been lacking in the literature. We have identified optimal conditions to achieve this conversion in good yields and have minimized formation of the bis-coupling product. The newly identified protocol involving the use of a syringe pump has been extended to other symmetrical diiodo(hetero)arenes.",
keywords = "1,4-Diiodo-2,3,5,6-tetrafluorobenzene, Coupling reactions, Crystal engineering, Halogen bond, Monocoupling, Polyfluorinated aromatics, LIGHT-EMITTING-DIODES, SEMICONDUCTORS, REMARKABLE ABILITY",
author = "Alexander Sapegin and Mikhail Krasavin",
year = "2018",
month = may,
day = "16",
doi = "10.1016/j.tetlet.2018.04.015",
language = "English",
volume = "59",
pages = "1948--1951",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier",
number = "20",

}

RIS

TY - JOUR

T1 - Efficient Suzuki-Miyaura mono-arylation of symmetrical diiodo(hetero)arenes

AU - Sapegin, Alexander

AU - Krasavin, Mikhail

PY - 2018/5/16

Y1 - 2018/5/16

N2 - A reliable protocol for converting 1,4-diiodo-2,3,5,6-tetrafluorobenzene into 1-(hetero)aryl-4-iodo-2,3,5,6-tetrafluorobenzene derivatives has been lacking in the literature. We have identified optimal conditions to achieve this conversion in good yields and have minimized formation of the bis-coupling product. The newly identified protocol involving the use of a syringe pump has been extended to other symmetrical diiodo(hetero)arenes.

AB - A reliable protocol for converting 1,4-diiodo-2,3,5,6-tetrafluorobenzene into 1-(hetero)aryl-4-iodo-2,3,5,6-tetrafluorobenzene derivatives has been lacking in the literature. We have identified optimal conditions to achieve this conversion in good yields and have minimized formation of the bis-coupling product. The newly identified protocol involving the use of a syringe pump has been extended to other symmetrical diiodo(hetero)arenes.

KW - 1,4-Diiodo-2,3,5,6-tetrafluorobenzene

KW - Coupling reactions

KW - Crystal engineering

KW - Halogen bond

KW - Monocoupling

KW - Polyfluorinated aromatics

KW - LIGHT-EMITTING-DIODES

KW - SEMICONDUCTORS

KW - REMARKABLE ABILITY

UR - http://www.scopus.com/inward/record.url?scp=85045214785&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2018.04.015

DO - 10.1016/j.tetlet.2018.04.015

M3 - Article

AN - SCOPUS:85045214785

VL - 59

SP - 1948

EP - 1951

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 20

ER -

ID: 28584972