Research output: Contribution to journal › Article › peer-review
Double-preintercalated vanadium oxide as a novel cathode material for magnesium-ion batteries. / -, Со Мин Тейн; Попов, Андрей Юрьевич; Толстопятова, Елена Геннадьевна; Yang, Peixia; Кондратьев, Вениамин Владимирович.
In: Materials Letters, Vol. 412, 140443, 01.06.2026.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Double-preintercalated vanadium oxide as a novel cathode material for magnesium-ion batteries
AU - -, Со Мин Тейн
AU - Попов, Андрей Юрьевич
AU - Толстопятова, Елена Геннадьевна
AU - Yang, Peixia
AU - Кондратьев, Вениамин Владимирович
PY - 2026/6/1
Y1 - 2026/6/1
N2 - Vanadium oxide double-preintercalated with Al3+ and poly(3,4-ethylenedioxythiophene) (Al0.18V2O5/PEDOT) was synthesized using a two-step hydrothermal method. The presence of Al3+ ions in the layered structure of Al0.18V2O5 and PEDOT in the double-preintercalated material was confirmed. The electrochemical performance of Al0.18V2O5/PEDOT cathodes in Mg2+-containing acetonitrile electrolyte was investigated by cyclic voltammetry and galvanostatic charge–discharge. The large interlayer distance of 14.02 Å allows Al0.18V2O5/PEDOT to reversibly intercalate magnesium ions into its crystal lattice. The cathodes achieved a high reversible capacity of 138 mAh·g−1 at a low current density (0.02 A·g−1) and demonstrated superior cycling performance, retaining 95.5% of capacity after 500 cycles at 0.1 A·g−1. This confirms that the dual modification approach is efficient for obtaining advanced magnesium-ion battery cathodes.
AB - Vanadium oxide double-preintercalated with Al3+ and poly(3,4-ethylenedioxythiophene) (Al0.18V2O5/PEDOT) was synthesized using a two-step hydrothermal method. The presence of Al3+ ions in the layered structure of Al0.18V2O5 and PEDOT in the double-preintercalated material was confirmed. The electrochemical performance of Al0.18V2O5/PEDOT cathodes in Mg2+-containing acetonitrile electrolyte was investigated by cyclic voltammetry and galvanostatic charge–discharge. The large interlayer distance of 14.02 Å allows Al0.18V2O5/PEDOT to reversibly intercalate magnesium ions into its crystal lattice. The cathodes achieved a high reversible capacity of 138 mAh·g−1 at a low current density (0.02 A·g−1) and demonstrated superior cycling performance, retaining 95.5% of capacity after 500 cycles at 0.1 A·g−1. This confirms that the dual modification approach is efficient for obtaining advanced magnesium-ion battery cathodes.
KW - Al0.18V2O5/PEDOT cathode
KW - Electrochemical performance
KW - Magnesium ion battery
KW - Preintercalated vanadium oxide
UR - https://www.mendeley.com/catalogue/4f367072-9f7e-364a-9657-7a7152d5312c/
U2 - 10.1016/j.matlet.2026.140443
DO - 10.1016/j.matlet.2026.140443
M3 - Article
VL - 412
JO - Materials Letters
JF - Materials Letters
SN - 0167-577X
M1 - 140443
ER -
ID: 150508867