Research output: Contribution to journal › Article › peer-review
Dialkyl diazomalonates in transition-metal-free, thermally promoted, diastereoselective wolff β-lactam synthesis. / Synofzik, Judith; Bakulina, Olga; Dar'in, Dmitry; Kantin, Grigory; Krasavin, Mikhail.
In: Synlett, Vol. 31, No. 13, 12.08.2020, p. 1273-1276.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Dialkyl diazomalonates in transition-metal-free, thermally promoted, diastereoselective wolff β-lactam synthesis
AU - Synofzik, Judith
AU - Bakulina, Olga
AU - Dar'in, Dmitry
AU - Kantin, Grigory
AU - Krasavin, Mikhail
N1 - Publisher Copyright: © 2020 Georg Thieme Verlag. All rights reserved.
PY - 2020/8/12
Y1 - 2020/8/12
N2 - Metal-free, thermally promoted synthesis of 3-alkoxy-3-alkoxycarbonyl-2-azetidinones via the Wolff-Staudinger β-lactam synthesis using dialkyl diazomalonates is described. The reaction appears fairly general and delivers only one diastereomer.
AB - Metal-free, thermally promoted synthesis of 3-alkoxy-3-alkoxycarbonyl-2-azetidinones via the Wolff-Staudinger β-lactam synthesis using dialkyl diazomalonates is described. The reaction appears fairly general and delivers only one diastereomer.
KW - diazomalonates
KW - metal-free
KW - thermal
KW - Wolff rearrangement
KW - β-lactam
KW - REARRANGEMENT
KW - CYCLOADDITION
KW - PYROLYSIS
KW - beta-lactam
UR - http://www.scopus.com/inward/record.url?scp=85089092713&partnerID=8YFLogxK
U2 - 10.1055/s-0040-1707811
DO - 10.1055/s-0040-1707811
M3 - Article
AN - SCOPUS:85089092713
VL - 31
SP - 1273
EP - 1276
JO - Synlett
JF - Synlett
SN - 0936-5214
IS - 13
ER -
ID: 61589552