Standard

Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores. / Добрынин, Михаил Валерьевич; Касаткина, Светлана Олеговна; Байков, Сергей Валентинович; Савко, Полина Юрьевна; Антонов, Никита Сергеевич; Михердов, Александр Сергеевич; Боярский, Вадим Павлович; Исламова, Регина Маратовна.

In: Dalton Transactions, Vol. 50, No. 42, 14.11.2021, p. 14994-14999.

Research output: Contribution to journal › Article › peer-review

Harvard

Добрынин, МВ, Касаткина, СО, Байков, СВ, Савко, ПЮ, Антонов, НС, Михердов, АС, Боярский, ВП & Исламова, РМ 2021, 'Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores', Dalton Transactions, vol. 50, no. 42, pp. 14994-14999. https://doi.org/10.1039/D1DT02823E

APA

Добрынин, М. В., Касаткина, С. О., Байков, С. В., Савко, П. Ю., Антонов, Н. С., Михердов, А. С., Боярский, В. П., & Исламова, Р. М. (2021). Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores. Dalton Transactions, 50(42), 14994-14999. https://doi.org/10.1039/D1DT02823E

Vancouver

Добрынин МВ, Касаткина СО, Байков СВ, Савко ПЮ, Антонов НС, Михердов АС et al. Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores. Dalton Transactions. 2021 Nov 14;50(42):14994-14999. https://doi.org/10.1039/D1DT02823E

Author

Добрынин, Михаил Валерьевич ; Касаткина, Светлана Олеговна ; Байков, Сергей Валентинович ; Савко, Полина Юрьевна ; Антонов, Никита Сергеевич ; Михердов, Александр Сергеевич ; Боярский, Вадим Павлович ; Исламова, Регина Маратовна. / Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores. In: Dalton Transactions. 2021 ; Vol. 50, No. 42. pp. 14994-14999.

BibTeX

@article{7dd1b6960f3340dc8def1444f3416f64,
title = "Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores",
abstract = "C,N-Chelate deprotonated diaminocarbene platinum(ii) complexes were synthesized by coupling coordinated isocyanides and azinyl-substituted ureas. The complexes act as catalysts of α,ω-divinylpolydimethylsiloxane and poly(dimethylsiloxane-co-methylhydrosiloxane) hydrosilylation cross-linking. Silicone rubbers obtained with (aminoisoquinoline)-containing complex 3d exhibit temperature-responsive luminescence. Their emission changes irreversibly when heated from 80-100 °C (green radiation) to 120 °C or more (blue radiation).",
keywords = "CROSS-LINKING, CYCLOMETALATED COMPLEXES, ISONITRILES, POLYSILOXANES, PT(II) COMPLEXES, PT-II, ROUTE",
author = "Добрынин, {Михаил Валерьевич} and Касаткина, {Светлана Олеговна} and Байков, {Сергей Валентинович} and Савко, {Полина Юрьевна} and Антонов, {Никита Сергеевич} and Михердов, {Александр Сергеевич} and Боярский, {Вадим Павлович} and Исламова, {Регина Маратовна}",
note = "Publisher Copyright: {\textcopyright} 2021 The Royal Society of Chemistry.",
year = "2021",
month = nov,
day = "14",
doi = "10.1039/D1DT02823E",
language = "English",
volume = "50",
pages = "14994--14999",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "42",

}

RIS

TY - JOUR

T1 - Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: both catalysts and luminophores

AU - Добрынин, Михаил Валерьевич

AU - Касаткина, Светлана Олеговна

AU - Байков, Сергей Валентинович

AU - Савко, Полина Юрьевна

AU - Антонов, Никита Сергеевич

AU - Михердов, Александр Сергеевич

AU - Боярский, Вадим Павлович

AU - Исламова, Регина Маратовна

N1 - Publisher Copyright: © 2021 The Royal Society of Chemistry.

PY - 2021/11/14

Y1 - 2021/11/14

N2 - C,N-Chelate deprotonated diaminocarbene platinum(ii) complexes were synthesized by coupling coordinated isocyanides and azinyl-substituted ureas. The complexes act as catalysts of α,ω-divinylpolydimethylsiloxane and poly(dimethylsiloxane-co-methylhydrosiloxane) hydrosilylation cross-linking. Silicone rubbers obtained with (aminoisoquinoline)-containing complex 3d exhibit temperature-responsive luminescence. Their emission changes irreversibly when heated from 80-100 °C (green radiation) to 120 °C or more (blue radiation).

AB - C,N-Chelate deprotonated diaminocarbene platinum(ii) complexes were synthesized by coupling coordinated isocyanides and azinyl-substituted ureas. The complexes act as catalysts of α,ω-divinylpolydimethylsiloxane and poly(dimethylsiloxane-co-methylhydrosiloxane) hydrosilylation cross-linking. Silicone rubbers obtained with (aminoisoquinoline)-containing complex 3d exhibit temperature-responsive luminescence. Their emission changes irreversibly when heated from 80-100 °C (green radiation) to 120 °C or more (blue radiation).

KW - CROSS-LINKING

KW - CYCLOMETALATED COMPLEXES

KW - ISONITRILES

KW - POLYSILOXANES

KW - PT(II) COMPLEXES

KW - PT-II

KW - ROUTE

UR - http://www.scopus.com/inward/record.url?scp=85118918039&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/a8819e6e-9c0a-343f-809b-8dc049db6ba3/

U2 - 10.1039/D1DT02823E

DO - 10.1039/D1DT02823E

M3 - Article

VL - 50

SP - 14994

EP - 14999

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 42

ER -

ID: 87436551