Research output: Contribution to journal › Article › peer-review
C,N-Chelate deprotonated diaminocarbene platinum(ii) complexes were synthesized by coupling coordinated isocyanides and azinyl-substituted ureas. The complexes act as catalysts of α,ω-divinylpolydimethylsiloxane and poly(dimethylsiloxane-co-methylhydrosiloxane) hydrosilylation cross-linking. Silicone rubbers obtained with (aminoisoquinoline)-containing complex 3d exhibit temperature-responsive luminescence. Their emission changes irreversibly when heated from 80-100 °C (green radiation) to 120 °C or more (blue radiation).
Original language | English |
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Pages (from-to) | 14994-14999 |
Number of pages | 6 |
Journal | Dalton Transactions |
Volume | 50 |
Issue number | 42 |
Early online date | 21 Oct 2021 |
DOIs | |
State | Published - 14 Nov 2021 |
ID: 87436551