DOI

C,N-Chelate deprotonated diaminocarbene platinum(ii) complexes were synthesized by coupling coordinated isocyanides and azinyl-substituted ureas. The complexes act as catalysts of α,ω-divinylpolydimethylsiloxane and poly(dimethylsiloxane-co-methylhydrosiloxane) hydrosilylation cross-linking. Silicone rubbers obtained with (aminoisoquinoline)-containing complex 3d exhibit temperature-responsive luminescence. Their emission changes irreversibly when heated from 80-100 °C (green radiation) to 120 °C or more (blue radiation).

Original languageEnglish
Pages (from-to)14994-14999
Number of pages6
JournalDalton Transactions
Volume50
Issue number42
Early online date21 Oct 2021
DOIs
StatePublished - 14 Nov 2021

    Research areas

  • CROSS-LINKING, CYCLOMETALATED COMPLEXES, ISONITRILES, POLYSILOXANES, PT(II) COMPLEXES, PT-II, ROUTE

    Scopus subject areas

  • Inorganic Chemistry

ID: 87436551