Research output: Contribution to journal › Article › peer-review
Delayed Fluorescence of Dyes Sensitized by Eu3+ Chelate Nanoparticles. / Mironov, Leonid Yu; Parfenov, Peter S.; Shurukhina, Anna V.; Lebedev, Yaroslav I.; Metlenko, Anastasiya A.
In: Journal of Physical Chemistry C, Vol. 121, No. 36, 14.09.2017, p. 19958-19965.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Delayed Fluorescence of Dyes Sensitized by Eu3+ Chelate Nanoparticles
AU - Mironov, Leonid Yu
AU - Parfenov, Peter S.
AU - Shurukhina, Anna V.
AU - Lebedev, Yaroslav I.
AU - Metlenko, Anastasiya A.
PY - 2017/9/14
Y1 - 2017/9/14
N2 - Dye-doped nanoparticles of Eu3+ chelate complexes with naphtoyltrifluoroacetone and 1,10-phenanthroline were synthesized using two different reprecipitation techniques. The nanoparticles were characterized by atomic force microscopy, absorption spectroscopy, steady-state, and time-resolved fluorescence spectroscopy. Fluorescent spectroscopy of chelate nanoparticles doped with Oxazine 170 and Nile blue dyes indicates that a single dye molecule efficiently quenches luminescence of more than a hundred chelates. The Eu3+ chelates have a significantly longer luminescence lifetime than organic dyes, which leads to the appearance of delayed dyes fluorescence with microsecond lifetimes. The fluorescence brightness of dye-doped chelate nanoparticles was determined to be 50 times higher than that of a single Rhodamine 6G molecule. The combination of high fluorescence brightness and long fluorescence lifetime of the dye-doped chelate nanoparticles is promising for time-gated applications. (Graph Presented).
AB - Dye-doped nanoparticles of Eu3+ chelate complexes with naphtoyltrifluoroacetone and 1,10-phenanthroline were synthesized using two different reprecipitation techniques. The nanoparticles were characterized by atomic force microscopy, absorption spectroscopy, steady-state, and time-resolved fluorescence spectroscopy. Fluorescent spectroscopy of chelate nanoparticles doped with Oxazine 170 and Nile blue dyes indicates that a single dye molecule efficiently quenches luminescence of more than a hundred chelates. The Eu3+ chelates have a significantly longer luminescence lifetime than organic dyes, which leads to the appearance of delayed dyes fluorescence with microsecond lifetimes. The fluorescence brightness of dye-doped chelate nanoparticles was determined to be 50 times higher than that of a single Rhodamine 6G molecule. The combination of high fluorescence brightness and long fluorescence lifetime of the dye-doped chelate nanoparticles is promising for time-gated applications. (Graph Presented).
UR - http://www.scopus.com/inward/record.url?scp=85029512990&partnerID=8YFLogxK
U2 - 10.1021/acs.jpcc.7b03648
DO - 10.1021/acs.jpcc.7b03648
M3 - Article
AN - SCOPUS:85029512990
VL - 121
SP - 19958
EP - 19965
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 36
ER -
ID: 36681434