DOI

  • Leonid Yu Mironov
  • Peter S. Parfenov
  • Anna V. Shurukhina
  • Yaroslav I. Lebedev
  • Anastasiya A. Metlenko

Dye-doped nanoparticles of Eu3+ chelate complexes with naphtoyltrifluoroacetone and 1,10-phenanthroline were synthesized using two different reprecipitation techniques. The nanoparticles were characterized by atomic force microscopy, absorption spectroscopy, steady-state, and time-resolved fluorescence spectroscopy. Fluorescent spectroscopy of chelate nanoparticles doped with Oxazine 170 and Nile blue dyes indicates that a single dye molecule efficiently quenches luminescence of more than a hundred chelates. The Eu3+ chelates have a significantly longer luminescence lifetime than organic dyes, which leads to the appearance of delayed dyes fluorescence with microsecond lifetimes. The fluorescence brightness of dye-doped chelate nanoparticles was determined to be 50 times higher than that of a single Rhodamine 6G molecule. The combination of high fluorescence brightness and long fluorescence lifetime of the dye-doped chelate nanoparticles is promising for time-gated applications. (Graph Presented).

Original languageEnglish
Pages (from-to)19958-19965
Number of pages8
JournalJournal of Physical Chemistry C
Volume121
Issue number36
DOIs
StatePublished - 14 Sep 2017

    Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

ID: 36681434