Research output: Contribution to journal › Article › peer-review
Dehydration-driven evolution of topological complexity in ethylamoniumuranyl selenates. / Gurzhiy, Vladislav V.; Krivovichev, Sergey V.; Tananaev, Ivan G.
In: Journal of Solid State Chemistry, Vol. 247, No. 1 March, 01.03.2017, p. 105-112.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Dehydration-driven evolution of topological complexity in ethylamoniumuranyl selenates
AU - Gurzhiy, Vladislav V.
AU - Krivovichev, Sergey V.
AU - Tananaev, Ivan G.
PY - 2017/3/1
Y1 - 2017/3/1
N2 - Single crystals of four novel uranyl selenate and selenite-selenate oxysalts with protonated ethylamine molecules, (C2H8N)2[(UO2)(SeO4)2(H2O)](H2O) (I), (C2H8N)3[(UO2)(SeO4)2(HSeO4)] (II), (C2H8N)[(UO2)(SeO4)(HSeO3)] (III), and (C2H8N)(H3O)[(UO2)(SeO4)2(H2O)] (IV) have been prepared by isothermal evaporation from aqueous solutions. Uranyl-containing 1D and 2D units have been investigated using topological approach and information-based complexity measurements that demonstrate the evolution of structural units and the increase of topological complexity with the decrease of H2O content.
AB - Single crystals of four novel uranyl selenate and selenite-selenate oxysalts with protonated ethylamine molecules, (C2H8N)2[(UO2)(SeO4)2(H2O)](H2O) (I), (C2H8N)3[(UO2)(SeO4)2(HSeO4)] (II), (C2H8N)[(UO2)(SeO4)(HSeO3)] (III), and (C2H8N)(H3O)[(UO2)(SeO4)2(H2O)] (IV) have been prepared by isothermal evaporation from aqueous solutions. Uranyl-containing 1D and 2D units have been investigated using topological approach and information-based complexity measurements that demonstrate the evolution of structural units and the increase of topological complexity with the decrease of H2O content.
U2 - 10.1016/j.jssc.2017.01.005
DO - 10.1016/j.jssc.2017.01.005
M3 - Article
VL - 247
SP - 105
EP - 112
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 1 March
ER -
ID: 7733389