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Degree of dissociation of electrolytes in aqueous solutions as obtained from NMR-relaxation data. / Chizhik, V. I.; Matveev, V. V.; Mikhailov, V. I.; Klykova, L. M.

In: Russian Journal of Physical Chemistry A, Vol. 72, No. 4, 04.1998, p. 577-581.

Research output: Contribution to journal › Article › peer-review

Harvard

Chizhik, VI, Matveev, VV, Mikhailov, VI & Klykova, LM 1998, 'Degree of dissociation of electrolytes in aqueous solutions as obtained from NMR-relaxation data', Russian Journal of Physical Chemistry A, vol. 72, no. 4, pp. 577-581.

APA

Chizhik, V. I., Matveev, V. V., Mikhailov, V. I., & Klykova, L. M. (1998). Degree of dissociation of electrolytes in aqueous solutions as obtained from NMR-relaxation data. Russian Journal of Physical Chemistry A, 72(4), 577-581.

Vancouver

Chizhik VI, Matveev VV, Mikhailov VI, Klykova LM. Degree of dissociation of electrolytes in aqueous solutions as obtained from NMR-relaxation data. Russian Journal of Physical Chemistry A. 1998 Apr;72(4):577-581.

Author

Chizhik, V. I. ; Matveev, V. V. ; Mikhailov, V. I. ; Klykova, L. M. / Degree of dissociation of electrolytes in aqueous solutions as obtained from NMR-relaxation data. In: Russian Journal of Physical Chemistry A. 1998 ; Vol. 72, No. 4. pp. 577-581.

BibTeX

@article{7e254d344bd44213824482a6ee8083eb,
title = "Degree of dissociation of electrolytes in aqueous solutions as obtained from NMR-relaxation data",
abstract = "The additivity in the influence of cations and anions on the rate of relaxation of the nuclei of the solvent (water) molecule is studied. The dissociation of a number of electrolytes is studied. In some cases, the dissociation may be considered complete up to the limits of solubility (NaCl, NaNO3, RbCl, NaF). However, for a number of simple electrolytes, such as CaCl2, CaBr2, Na2SO4, etc., a deviation from the additivity rule is observable at moderate concentrations. The conclusion is made that contact or separated ionic pairs are formed.",
author = "Chizhik, {V. I.} and Matveev, {V. V.} and Mikhailov, {V. I.} and Klykova, {L. M.}",
year = "1998",
month = apr,
language = "English",
volume = "72",
pages = "577--581",
journal = "Russian Journal of Physical Chemistry A",
issn = "0036-0244",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Degree of dissociation of electrolytes in aqueous solutions as obtained from NMR-relaxation data

AU - Chizhik, V. I.

AU - Matveev, V. V.

AU - Mikhailov, V. I.

AU - Klykova, L. M.

PY - 1998/4

Y1 - 1998/4

N2 - The additivity in the influence of cations and anions on the rate of relaxation of the nuclei of the solvent (water) molecule is studied. The dissociation of a number of electrolytes is studied. In some cases, the dissociation may be considered complete up to the limits of solubility (NaCl, NaNO3, RbCl, NaF). However, for a number of simple electrolytes, such as CaCl2, CaBr2, Na2SO4, etc., a deviation from the additivity rule is observable at moderate concentrations. The conclusion is made that contact or separated ionic pairs are formed.

AB - The additivity in the influence of cations and anions on the rate of relaxation of the nuclei of the solvent (water) molecule is studied. The dissociation of a number of electrolytes is studied. In some cases, the dissociation may be considered complete up to the limits of solubility (NaCl, NaNO3, RbCl, NaF). However, for a number of simple electrolytes, such as CaCl2, CaBr2, Na2SO4, etc., a deviation from the additivity rule is observable at moderate concentrations. The conclusion is made that contact or separated ionic pairs are formed.

UR - http://www.scopus.com/inward/record.url?scp=0032388351&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:14844308797

VL - 72

SP - 577

EP - 581

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

SN - 0036-0244

IS - 4

ER -

ID: 37037350