Research output: Contribution to journal › Article › peer-review
Cu(II) 2-iodobenzoates : precursor-dependent formation of paddlewheel-like [Cu2(OOCR)4L2] or [Cu2L4(OOCR)2Cl2] binuclear complexes. / Bondarenko, Mikhail A.; Novikov, Alexander S.; Korolkov, Ilya V.; Sokolov, Maxim N.; Adonin, Sergey A.
In: Inorganica Chimica Acta, Vol. 524, 120436, 01.09.2021.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Cu(II) 2-iodobenzoates
T2 - precursor-dependent formation of paddlewheel-like [Cu2(OOCR)4L2] or [Cu2L4(OOCR)2Cl2] binuclear complexes
AU - Bondarenko, Mikhail A.
AU - Novikov, Alexander S.
AU - Korolkov, Ilya V.
AU - Sokolov, Maxim N.
AU - Adonin, Sergey A.
N1 - Publisher Copyright: © 2021 Elsevier B.V. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/9/1
Y1 - 2021/9/1
N2 - The outcomes of reactions of Cu(II) salts with 2-iodobenzoic acid (2-IBA) in acetonitrile in presence of different substituted pyridines (Py, 4-MePy, 4-EtPy, 3,4-MePy, 2,6-MePy, 2,4,6-MePy and 2,6-BrPy) (L) depend on the nature of Cu-containing precursors and L, resulting in [Cu2(2-IBA)4(CH3CN)2], [Cu2(2-IBA)4L2] or [Cu2L4(2-IBA)2Cl2] complexes. In total, seven complexes were prepared and characterized by X-ray diffractometry. The role of halogen bonding (XB) in the structures was examined by theoretical methods.
AB - The outcomes of reactions of Cu(II) salts with 2-iodobenzoic acid (2-IBA) in acetonitrile in presence of different substituted pyridines (Py, 4-MePy, 4-EtPy, 3,4-MePy, 2,6-MePy, 2,4,6-MePy and 2,6-BrPy) (L) depend on the nature of Cu-containing precursors and L, resulting in [Cu2(2-IBA)4(CH3CN)2], [Cu2(2-IBA)4L2] or [Cu2L4(2-IBA)2Cl2] complexes. In total, seven complexes were prepared and characterized by X-ray diffractometry. The role of halogen bonding (XB) in the structures was examined by theoretical methods.
KW - Copper
KW - DFT calculations
KW - Halogen bonding
KW - N-donor ligands
KW - Supramolecular contacts
KW - MOLECULAR-STRUCTURE
KW - DONOR
KW - COPPER(II)
KW - SUBSTITUENTS
KW - LUMINESCENT PROPERTIES
KW - CARBOXYLATE ANION
KW - HYDROGEN
KW - EUROPIUM(III)
KW - COORDINATION POLYMERS
KW - HALOGEN BOND
UR - http://www.scopus.com/inward/record.url?scp=85105595781&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2021.120436
DO - 10.1016/j.ica.2021.120436
M3 - Article
AN - SCOPUS:85105595781
VL - 524
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
M1 - 120436
ER -
ID: 77245287