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Cu(II) 2-iodobenzoates : precursor-dependent formation of paddlewheel-like [Cu2(OOCR)4L2] or [Cu2L4(OOCR)2Cl2] binuclear complexes. / Bondarenko, Mikhail A.; Novikov, Alexander S.; Korolkov, Ilya V.; Sokolov, Maxim N.; Adonin, Sergey A.

In: Inorganica Chimica Acta, Vol. 524, 120436, 01.09.2021.

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Bondarenko, Mikhail A. ; Novikov, Alexander S. ; Korolkov, Ilya V. ; Sokolov, Maxim N. ; Adonin, Sergey A. / Cu(II) 2-iodobenzoates : precursor-dependent formation of paddlewheel-like [Cu2(OOCR)4L2] or [Cu2L4(OOCR)2Cl2] binuclear complexes. In: Inorganica Chimica Acta. 2021 ; Vol. 524.

BibTeX

@article{803c0b8f0aa74beb8f45dac07ecc2858,
title = "Cu(II) 2-iodobenzoates: precursor-dependent formation of paddlewheel-like [Cu2(OOCR)4L2] or [Cu2L4(OOCR)2Cl2] binuclear complexes",
abstract = "The outcomes of reactions of Cu(II) salts with 2-iodobenzoic acid (2-IBA) in acetonitrile in presence of different substituted pyridines (Py, 4-MePy, 4-EtPy, 3,4-MePy, 2,6-MePy, 2,4,6-MePy and 2,6-BrPy) (L) depend on the nature of Cu-containing precursors and L, resulting in [Cu2(2-IBA)4(CH3CN)2], [Cu2(2-IBA)4L2] or [Cu2L4(2-IBA)2Cl2] complexes. In total, seven complexes were prepared and characterized by X-ray diffractometry. The role of halogen bonding (XB) in the structures was examined by theoretical methods.",
keywords = "Copper, DFT calculations, Halogen bonding, N-donor ligands, Supramolecular contacts, MOLECULAR-STRUCTURE, DONOR, COPPER(II), SUBSTITUENTS, LUMINESCENT PROPERTIES, CARBOXYLATE ANION, HYDROGEN, EUROPIUM(III), COORDINATION POLYMERS, HALOGEN BOND",
author = "Bondarenko, {Mikhail A.} and Novikov, {Alexander S.} and Korolkov, {Ilya V.} and Sokolov, {Maxim N.} and Adonin, {Sergey A.}",
note = "Publisher Copyright: {\textcopyright} 2021 Elsevier B.V. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = sep,
day = "1",
doi = "10.1016/j.ica.2021.120436",
language = "English",
volume = "524",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Cu(II) 2-iodobenzoates

T2 - precursor-dependent formation of paddlewheel-like [Cu2(OOCR)4L2] or [Cu2L4(OOCR)2Cl2] binuclear complexes

AU - Bondarenko, Mikhail A.

AU - Novikov, Alexander S.

AU - Korolkov, Ilya V.

AU - Sokolov, Maxim N.

AU - Adonin, Sergey A.

N1 - Publisher Copyright: © 2021 Elsevier B.V. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/9/1

Y1 - 2021/9/1

N2 - The outcomes of reactions of Cu(II) salts with 2-iodobenzoic acid (2-IBA) in acetonitrile in presence of different substituted pyridines (Py, 4-MePy, 4-EtPy, 3,4-MePy, 2,6-MePy, 2,4,6-MePy and 2,6-BrPy) (L) depend on the nature of Cu-containing precursors and L, resulting in [Cu2(2-IBA)4(CH3CN)2], [Cu2(2-IBA)4L2] or [Cu2L4(2-IBA)2Cl2] complexes. In total, seven complexes were prepared and characterized by X-ray diffractometry. The role of halogen bonding (XB) in the structures was examined by theoretical methods.

AB - The outcomes of reactions of Cu(II) salts with 2-iodobenzoic acid (2-IBA) in acetonitrile in presence of different substituted pyridines (Py, 4-MePy, 4-EtPy, 3,4-MePy, 2,6-MePy, 2,4,6-MePy and 2,6-BrPy) (L) depend on the nature of Cu-containing precursors and L, resulting in [Cu2(2-IBA)4(CH3CN)2], [Cu2(2-IBA)4L2] or [Cu2L4(2-IBA)2Cl2] complexes. In total, seven complexes were prepared and characterized by X-ray diffractometry. The role of halogen bonding (XB) in the structures was examined by theoretical methods.

KW - Copper

KW - DFT calculations

KW - Halogen bonding

KW - N-donor ligands

KW - Supramolecular contacts

KW - MOLECULAR-STRUCTURE

KW - DONOR

KW - COPPER(II)

KW - SUBSTITUENTS

KW - LUMINESCENT PROPERTIES

KW - CARBOXYLATE ANION

KW - HYDROGEN

KW - EUROPIUM(III)

KW - COORDINATION POLYMERS

KW - HALOGEN BOND

UR - http://www.scopus.com/inward/record.url?scp=85105595781&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2021.120436

DO - 10.1016/j.ica.2021.120436

M3 - Article

AN - SCOPUS:85105595781

VL - 524

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 120436

ER -

ID: 77245287