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Crystal structures and thermal expansion of Sr1–xBaxBi2B2O7 solid solutions. / Bubnova, R. S.; Shablinskii, A. P.; Volkov, S. N.; Filatov, S. K.; Krzhizhanovskaya, M. G.; Ugolkov, V. L.

In: Glass Physics and Chemistry, Vol. 42, No. 4, 10.08.2016, p. 337-348.

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Bubnova, R. S. ; Shablinskii, A. P. ; Volkov, S. N. ; Filatov, S. K. ; Krzhizhanovskaya, M. G. ; Ugolkov, V. L. / Crystal structures and thermal expansion of Sr1–xBaxBi2B2O7 solid solutions. In: Glass Physics and Chemistry. 2016 ; Vol. 42, No. 4. pp. 337-348.

BibTeX

@article{a246b43b4e224245a57857e6f048ae29,
title = "Crystal structures and thermal expansion of Sr1–xBaxBi2B2O7 solid solutions",
abstract = "A series of Sr1–xBaxBi2B2O7 solid solutions (x = 0–1) have been synthesized by crystallization from glass ceramics. The crystal structures of solid solutions at x = 0.65 and x = 1 were solved by direct methods of X-ray diffraction from single crystal data and refined in a reduced cell ((aBa = aSr/√3)) relative to SrBi2B2O7 in the same space group P63. Using the Rietveld method, the phase transition range at x = 0.65–0.70 with a reduction of the unit cell has been revealed. As was shown by method of high-temperature powder X-ray diffraction, the solid solutions demonstrated an anisotropic thermal expansion (TE) upon heating in air.",
keywords = "bismuth borates, crystal structure, immiscibility range, thermal expansion",
author = "Bubnova, {R. S.} and Shablinskii, {A. P.} and Volkov, {S. N.} and Filatov, {S. K.} and Krzhizhanovskaya, {M. G.} and Ugolkov, {V. L.}",
year = "2016",
month = aug,
day = "10",
doi = "10.1134/S1087659616040040",
language = "English",
volume = "42",
pages = "337--348",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Crystal structures and thermal expansion of Sr1–xBaxBi2B2O7 solid solutions

AU - Bubnova, R. S.

AU - Shablinskii, A. P.

AU - Volkov, S. N.

AU - Filatov, S. K.

AU - Krzhizhanovskaya, M. G.

AU - Ugolkov, V. L.

PY - 2016/8/10

Y1 - 2016/8/10

N2 - A series of Sr1–xBaxBi2B2O7 solid solutions (x = 0–1) have been synthesized by crystallization from glass ceramics. The crystal structures of solid solutions at x = 0.65 and x = 1 were solved by direct methods of X-ray diffraction from single crystal data and refined in a reduced cell ((aBa = aSr/√3)) relative to SrBi2B2O7 in the same space group P63. Using the Rietveld method, the phase transition range at x = 0.65–0.70 with a reduction of the unit cell has been revealed. As was shown by method of high-temperature powder X-ray diffraction, the solid solutions demonstrated an anisotropic thermal expansion (TE) upon heating in air.

AB - A series of Sr1–xBaxBi2B2O7 solid solutions (x = 0–1) have been synthesized by crystallization from glass ceramics. The crystal structures of solid solutions at x = 0.65 and x = 1 were solved by direct methods of X-ray diffraction from single crystal data and refined in a reduced cell ((aBa = aSr/√3)) relative to SrBi2B2O7 in the same space group P63. Using the Rietveld method, the phase transition range at x = 0.65–0.70 with a reduction of the unit cell has been revealed. As was shown by method of high-temperature powder X-ray diffraction, the solid solutions demonstrated an anisotropic thermal expansion (TE) upon heating in air.

KW - bismuth borates

KW - crystal structure

KW - immiscibility range

KW - thermal expansion

UR - http://www.scopus.com/inward/record.url?scp=84981275679&partnerID=8YFLogxK

U2 - 10.1134/S1087659616040040

DO - 10.1134/S1087659616040040

M3 - Article

AN - SCOPUS:84981275679

VL - 42

SP - 337

EP - 348

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 4

ER -

ID: 9147373