Research output: Contribution to journal › Article › peer-review
Cryoscopic study of aqueous solutions of sulfur-containing amino acids adducts of fullerene C60. / Mlhem, А.; Юрьев, Глеб Олегович; Ануфриков, Юрий Алексеевич; Пенькова, Анастасия Владимировна; Мурин, Игорь Васильевич; Чарыков, Н.А.; Kholmurodova, Dilafruz K.; Rizaev, Jasur A.; Kubaev, Aziz S.; Шаройко, Владимир Владимирович; Семёнов, Константин Николаевич.
In: Fullerenes Nanotubes and Carbon Nanostructures, Vol. 33, No. 12, 01.06.2025, p. 1240-1248.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Cryoscopic study of aqueous solutions of sulfur-containing amino acids adducts of fullerene C60
AU - Mlhem, А.
AU - Юрьев, Глеб Олегович
AU - Ануфриков, Юрий Алексеевич
AU - Пенькова, Анастасия Владимировна
AU - Мурин, Игорь Васильевич
AU - Чарыков, Н.А.
AU - Kholmurodova, Dilafruz K.
AU - Rizaev, Jasur A.
AU - Kubaev, Aziz S.
AU - Шаройко, Владимир Владимирович
AU - Семёнов, Константин Николаевич
PY - 2025/6/1
Y1 - 2025/6/1
N2 - The study presents cryoscopic investigation of binary systems containing adducts of fullerene C60 with sulfur-containing amino acids C60(C3H7NO2S)3 (adduct with L-cysteine, C60-Cys) and C60(C5H11NO2S)3 (adduct with L-methionine, C60-Met). Excess thermodynamic functions of solution components were calculated using a semi-empirical model Virial Decomposition Asymmetric Model (VD-AS). Adducts of fullerene C60 with sulfur-containing amino acids were characterized using 13C NMR, IR and UV/Vis spectroscopy, elemental analysis, and HPLC. Additionally, experimental data on the enthalpy of combustion of fullerene adducts, as well as concentration dependences of particle size distribution and ζ-potentials are presented.
AB - The study presents cryoscopic investigation of binary systems containing adducts of fullerene C60 with sulfur-containing amino acids C60(C3H7NO2S)3 (adduct with L-cysteine, C60-Cys) and C60(C5H11NO2S)3 (adduct with L-methionine, C60-Met). Excess thermodynamic functions of solution components were calculated using a semi-empirical model Virial Decomposition Asymmetric Model (VD-AS). Adducts of fullerene C60 with sulfur-containing amino acids were characterized using 13C NMR, IR and UV/Vis spectroscopy, elemental analysis, and HPLC. Additionally, experimental data on the enthalpy of combustion of fullerene adducts, as well as concentration dependences of particle size distribution and ζ-potentials are presented.
KW - Fullerene C60
KW - cryoscopy
KW - enthalpy of combustion
KW - l-cysteine
KW - l-methionine
UR - https://www.mendeley.com/catalogue/df38dcfa-2154-3033-a7b4-a7a829224ca2/
U2 - 10.1080/1536383x.2025.2496423
DO - 10.1080/1536383x.2025.2496423
M3 - Article
VL - 33
SP - 1240
EP - 1248
JO - Fullerenes Nanotubes and Carbon Nanostructures
JF - Fullerenes Nanotubes and Carbon Nanostructures
SN - 1536-383X
IS - 12
ER -
ID: 137983231