Standard

Copper polytellurite-chlorides with A2 + cations ([Formula presented], Pb) obtained by CVT reactions. / Zinyakhina, Diana O.; Siidra, Oleg I.; Charkin, Dmitri O.; Nazarchuk, Evgeniy V.; Bubnova, Rimma S.

In: Inorganic Chemistry Communications, Vol. 71, 01.09.2016, p. 94-97.

Research output: Contribution to journalArticlepeer-review

Harvard

APA

Vancouver

Author

Zinyakhina, Diana O. ; Siidra, Oleg I. ; Charkin, Dmitri O. ; Nazarchuk, Evgeniy V. ; Bubnova, Rimma S. / Copper polytellurite-chlorides with A2 + cations ([Formula presented], Pb) obtained by CVT reactions. In: Inorganic Chemistry Communications. 2016 ; Vol. 71. pp. 94-97.

BibTeX

@article{80c4a66343104d37bc8d8670129e66bb,
title = "Copper polytellurite-chlorides with A2 + cations ([Formula presented], Pb) obtained by CVT reactions",
abstract = "Two novel polytellurite-chlorides Pb5Cu2(Te4O11)Cl8 (1) and CdCu2(Te3O8)Cl2 (2) were obtained by a chemical vapor transport (CVT-reactions) reactions. The structure of 1 is based on [Pb5Cu2(Te4O11)]8 + one-dimensional blocks with full and partially occupied Cl sites around. The structure of 2 can be described as being formed by two types of one-dimensional units formed by Cd,Cu-centered polyhedra and TeO3, TeO4 pyramids sharing via common O atoms into electroneutral [CdCu2(Te3O8)Cl2]0 sheets. Obtaining of novel polytellurite-chlorides demonstrates effectiveness of CVT techniques for preparation of different tellurite-based complex layered materials.",
keywords = "Copper, CVT-reactions, Lone-pair, Polytellurites, Single crystal X-ray diffraction, Tellurium",
author = "Zinyakhina, {Diana O.} and Siidra, {Oleg I.} and Charkin, {Dmitri O.} and Nazarchuk, {Evgeniy V.} and Bubnova, {Rimma S.}",
year = "2016",
month = sep,
day = "1",
doi = "10.1016/j.inoche.2016.07.007",
language = "English",
volume = "71",
pages = "94--97",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Copper polytellurite-chlorides with A2 + cations ([Formula presented], Pb) obtained by CVT reactions

AU - Zinyakhina, Diana O.

AU - Siidra, Oleg I.

AU - Charkin, Dmitri O.

AU - Nazarchuk, Evgeniy V.

AU - Bubnova, Rimma S.

PY - 2016/9/1

Y1 - 2016/9/1

N2 - Two novel polytellurite-chlorides Pb5Cu2(Te4O11)Cl8 (1) and CdCu2(Te3O8)Cl2 (2) were obtained by a chemical vapor transport (CVT-reactions) reactions. The structure of 1 is based on [Pb5Cu2(Te4O11)]8 + one-dimensional blocks with full and partially occupied Cl sites around. The structure of 2 can be described as being formed by two types of one-dimensional units formed by Cd,Cu-centered polyhedra and TeO3, TeO4 pyramids sharing via common O atoms into electroneutral [CdCu2(Te3O8)Cl2]0 sheets. Obtaining of novel polytellurite-chlorides demonstrates effectiveness of CVT techniques for preparation of different tellurite-based complex layered materials.

AB - Two novel polytellurite-chlorides Pb5Cu2(Te4O11)Cl8 (1) and CdCu2(Te3O8)Cl2 (2) were obtained by a chemical vapor transport (CVT-reactions) reactions. The structure of 1 is based on [Pb5Cu2(Te4O11)]8 + one-dimensional blocks with full and partially occupied Cl sites around. The structure of 2 can be described as being formed by two types of one-dimensional units formed by Cd,Cu-centered polyhedra and TeO3, TeO4 pyramids sharing via common O atoms into electroneutral [CdCu2(Te3O8)Cl2]0 sheets. Obtaining of novel polytellurite-chlorides demonstrates effectiveness of CVT techniques for preparation of different tellurite-based complex layered materials.

KW - Copper

KW - CVT-reactions

KW - Lone-pair

KW - Polytellurites

KW - Single crystal X-ray diffraction

KW - Tellurium

UR - http://www.scopus.com/inward/record.url?scp=84978732467&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2016.07.007

DO - 10.1016/j.inoche.2016.07.007

M3 - Article

AN - SCOPUS:84978732467

VL - 71

SP - 94

EP - 97

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 9144607