Research output: Contribution to journal › Article › peer-review
Copper polytellurite-chlorides with A2 + cations ([Formula presented], Pb) obtained by CVT reactions. / Zinyakhina, Diana O.; Siidra, Oleg I.; Charkin, Dmitri O.; Nazarchuk, Evgeniy V.; Bubnova, Rimma S.
In: Inorganic Chemistry Communications, Vol. 71, 01.09.2016, p. 94-97.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Copper polytellurite-chlorides with A2 + cations ([Formula presented], Pb) obtained by CVT reactions
AU - Zinyakhina, Diana O.
AU - Siidra, Oleg I.
AU - Charkin, Dmitri O.
AU - Nazarchuk, Evgeniy V.
AU - Bubnova, Rimma S.
PY - 2016/9/1
Y1 - 2016/9/1
N2 - Two novel polytellurite-chlorides Pb5Cu2(Te4O11)Cl8 (1) and CdCu2(Te3O8)Cl2 (2) were obtained by a chemical vapor transport (CVT-reactions) reactions. The structure of 1 is based on [Pb5Cu2(Te4O11)]8 + one-dimensional blocks with full and partially occupied Cl sites around. The structure of 2 can be described as being formed by two types of one-dimensional units formed by Cd,Cu-centered polyhedra and TeO3, TeO4 pyramids sharing via common O atoms into electroneutral [CdCu2(Te3O8)Cl2]0 sheets. Obtaining of novel polytellurite-chlorides demonstrates effectiveness of CVT techniques for preparation of different tellurite-based complex layered materials.
AB - Two novel polytellurite-chlorides Pb5Cu2(Te4O11)Cl8 (1) and CdCu2(Te3O8)Cl2 (2) were obtained by a chemical vapor transport (CVT-reactions) reactions. The structure of 1 is based on [Pb5Cu2(Te4O11)]8 + one-dimensional blocks with full and partially occupied Cl sites around. The structure of 2 can be described as being formed by two types of one-dimensional units formed by Cd,Cu-centered polyhedra and TeO3, TeO4 pyramids sharing via common O atoms into electroneutral [CdCu2(Te3O8)Cl2]0 sheets. Obtaining of novel polytellurite-chlorides demonstrates effectiveness of CVT techniques for preparation of different tellurite-based complex layered materials.
KW - Copper
KW - CVT-reactions
KW - Lone-pair
KW - Polytellurites
KW - Single crystal X-ray diffraction
KW - Tellurium
UR - http://www.scopus.com/inward/record.url?scp=84978732467&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2016.07.007
DO - 10.1016/j.inoche.2016.07.007
M3 - Article
AN - SCOPUS:84978732467
VL - 71
SP - 94
EP - 97
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -
ID: 9144607