An ab initio method based on a complex-scaling approach and aimed at a rigorous QED description of autoionizing states is worked out. The autoionizing-state binding energies are treated nonperturbatively in αZ and include all the many-electron QED contributions up to the second order. The higher-order electron correlation, nuclear recoil, and nuclear polarization effects are taken into account as well. The developed formalism is demonstrated on the LL resonances in helium-like argon and uranium. The most accurate theoretical predictions for the binding energies are obtained.
Original languageEnglish
Article number032801
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume107
Issue number3
DOIs
StatePublished - 2023

ID: 104972578