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Comb-like polyelectrolytes – New surfactants with controlled solubilization capacity. / Fetin, P. A.; Lezov, A. A.; Fetina, V. I.; Kadnikov, M. V.; Tsvetkov, N. V.; Zorin, I. M.

In: Journal of Molecular Liquids, Vol. 357, 119085, 01.07.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Fetin, PA, Lezov, AA, Fetina, VI, Kadnikov, MV, Tsvetkov, NV & Zorin, IM 2022, 'Comb-like polyelectrolytes – New surfactants with controlled solubilization capacity', Journal of Molecular Liquids, vol. 357, 119085. https://doi.org/10.1016/j.molliq.2022.119085

APA

Fetin, P. A., Lezov, A. A., Fetina, V. I., Kadnikov, M. V., Tsvetkov, N. V., & Zorin, I. M. (2022). Comb-like polyelectrolytes – New surfactants with controlled solubilization capacity. Journal of Molecular Liquids, 357, [119085]. https://doi.org/10.1016/j.molliq.2022.119085

Vancouver

Fetin PA, Lezov AA, Fetina VI, Kadnikov MV, Tsvetkov NV, Zorin IM. Comb-like polyelectrolytes – New surfactants with controlled solubilization capacity. Journal of Molecular Liquids. 2022 Jul 1;357. 119085. https://doi.org/10.1016/j.molliq.2022.119085

Author

Fetin, P. A. ; Lezov, A. A. ; Fetina, V. I. ; Kadnikov, M. V. ; Tsvetkov, N. V. ; Zorin, I. M. / Comb-like polyelectrolytes – New surfactants with controlled solubilization capacity. In: Journal of Molecular Liquids. 2022 ; Vol. 357.

BibTeX

@article{4934c282bf02453d8afdaa952db8fb41,
title = "Comb-like polyelectrolytes – New surfactants with controlled solubilization capacity",
abstract = "Cationic surface-active monomers with 11-acryloyloxyundecyl tail in quaternary ammonium group and the corresponding comb-like polyelectrolytes are investigated. The sources of quaternary ammonium were aliphatic amines (trimethylamine and triethylamine) or aromatic and aliphatic cyclic amines (N-methylpiperidine, N-methylmorpholine, pyridine, quinoline). The monomer to polymer transformation increases the solubilization capacity of surfactant in one order of magnitude. The comb-like polyelectrolytes are capable to effective solubilization of hydrophobic probe over the wide concentration range including extremely low concentrations of the polymer. There aren't any precipitations of comb-like polyelectrolytes with temperature decrease unlike of many ionic low-molecular weight surfactants. Solubilization capacity of the hydrophobic probe by comb-like polyelectrolyte is slightly influenced by the molecular weight of the polymer and is determined by the nature of the ionic group of comb-like polyelectrolyte and counterion.",
keywords = "Comb-like polyelectrolytes, Light scattering, Micelles, Self-assembly, Solubilization, Structural design",
author = "Fetin, {P. A.} and Lezov, {A. A.} and Fetina, {V. I.} and Kadnikov, {M. V.} and Tsvetkov, {N. V.} and Zorin, {I. M.}",
note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",
year = "2022",
month = jul,
day = "1",
doi = "10.1016/j.molliq.2022.119085",
language = "English",
volume = "357",
journal = "Journal of Molecular Liquids",
issn = "0167-7322",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Comb-like polyelectrolytes – New surfactants with controlled solubilization capacity

AU - Fetin, P. A.

AU - Lezov, A. A.

AU - Fetina, V. I.

AU - Kadnikov, M. V.

AU - Tsvetkov, N. V.

AU - Zorin, I. M.

N1 - Publisher Copyright: © 2022 Elsevier B.V.

PY - 2022/7/1

Y1 - 2022/7/1

N2 - Cationic surface-active monomers with 11-acryloyloxyundecyl tail in quaternary ammonium group and the corresponding comb-like polyelectrolytes are investigated. The sources of quaternary ammonium were aliphatic amines (trimethylamine and triethylamine) or aromatic and aliphatic cyclic amines (N-methylpiperidine, N-methylmorpholine, pyridine, quinoline). The monomer to polymer transformation increases the solubilization capacity of surfactant in one order of magnitude. The comb-like polyelectrolytes are capable to effective solubilization of hydrophobic probe over the wide concentration range including extremely low concentrations of the polymer. There aren't any precipitations of comb-like polyelectrolytes with temperature decrease unlike of many ionic low-molecular weight surfactants. Solubilization capacity of the hydrophobic probe by comb-like polyelectrolyte is slightly influenced by the molecular weight of the polymer and is determined by the nature of the ionic group of comb-like polyelectrolyte and counterion.

AB - Cationic surface-active monomers with 11-acryloyloxyundecyl tail in quaternary ammonium group and the corresponding comb-like polyelectrolytes are investigated. The sources of quaternary ammonium were aliphatic amines (trimethylamine and triethylamine) or aromatic and aliphatic cyclic amines (N-methylpiperidine, N-methylmorpholine, pyridine, quinoline). The monomer to polymer transformation increases the solubilization capacity of surfactant in one order of magnitude. The comb-like polyelectrolytes are capable to effective solubilization of hydrophobic probe over the wide concentration range including extremely low concentrations of the polymer. There aren't any precipitations of comb-like polyelectrolytes with temperature decrease unlike of many ionic low-molecular weight surfactants. Solubilization capacity of the hydrophobic probe by comb-like polyelectrolyte is slightly influenced by the molecular weight of the polymer and is determined by the nature of the ionic group of comb-like polyelectrolyte and counterion.

KW - Comb-like polyelectrolytes

KW - Light scattering

KW - Micelles

KW - Self-assembly

KW - Solubilization

KW - Structural design

UR - http://www.scopus.com/inward/record.url?scp=85127758497&partnerID=8YFLogxK

U2 - 10.1016/j.molliq.2022.119085

DO - 10.1016/j.molliq.2022.119085

M3 - Article

AN - SCOPUS:85127758497

VL - 357

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

SN - 0167-7322

M1 - 119085

ER -

ID: 94652542