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Cobalt-doped hydroxyapatite nanoparticles as a new eco-friendly catalyst of luminol–H2O2 based chemiluminescence reaction : Study of key factors, improvement the activity and analytical application. / Vakh, Christina; Kuzmin, Artem; Sadetskaya, Anastasia; Bogdanova, Polina; Voznesenskiy, Mikhail; Osmolovskaya, Olga; Bulatov, Andrey.

In: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Vol. 237, 118382, 15.08.2020.

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@article{11799193fd194b808302dee9b492dc8a,
title = "Cobalt-doped hydroxyapatite nanoparticles as a new eco-friendly catalyst of luminol–H2O2 based chemiluminescence reaction: Study of key factors, improvement the activity and analytical application",
abstract = "In this study, a novel catalyst based on hydroxyapatite doped by cobalt for chemiluminescence reaction of luminol oxidation by H2O2 was suggested for the first time. The catalyst nanoparticles were synthesized by a hydrothermal method and characterized by various methods including density functional theory calculations. The impact of nanoparticles sizes, surface composition, contact efficiency and crystallinity on chemiluminescence intensity were investigated. The maximum chemiluminescence intensity was obtained for polycrystalline nanoparticles. This phenomenon was studied in detail and applied for chemiluminescence analysis for the first time. The chemiluminescence determination of sulfonamides as model analytes was considered. The sensing was based on sulfonamides-dependent quenching of the chemiluminescence intensity in the presence of novel catalyst existed as an aqueous suspension.",
keywords = "Catalysis, Chemiluminescence, Crystal parameters, Hydroxyapatite nanoparticles, Polycrystalline nanoparticles, Sulfonamides, SULFONAMIDES",
author = "Christina Vakh and Artem Kuzmin and Anastasia Sadetskaya and Polina Bogdanova and Mikhail Voznesenskiy and Olga Osmolovskaya and Andrey Bulatov",
year = "2020",
month = aug,
day = "15",
doi = "10.1016/j.saa.2020.118382",
language = "English",
volume = "237",
journal = "SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY",
issn = "1386-1425",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Cobalt-doped hydroxyapatite nanoparticles as a new eco-friendly catalyst of luminol–H2O2 based chemiluminescence reaction

T2 - Study of key factors, improvement the activity and analytical application

AU - Vakh, Christina

AU - Kuzmin, Artem

AU - Sadetskaya, Anastasia

AU - Bogdanova, Polina

AU - Voznesenskiy, Mikhail

AU - Osmolovskaya, Olga

AU - Bulatov, Andrey

PY - 2020/8/15

Y1 - 2020/8/15

N2 - In this study, a novel catalyst based on hydroxyapatite doped by cobalt for chemiluminescence reaction of luminol oxidation by H2O2 was suggested for the first time. The catalyst nanoparticles were synthesized by a hydrothermal method and characterized by various methods including density functional theory calculations. The impact of nanoparticles sizes, surface composition, contact efficiency and crystallinity on chemiluminescence intensity were investigated. The maximum chemiluminescence intensity was obtained for polycrystalline nanoparticles. This phenomenon was studied in detail and applied for chemiluminescence analysis for the first time. The chemiluminescence determination of sulfonamides as model analytes was considered. The sensing was based on sulfonamides-dependent quenching of the chemiluminescence intensity in the presence of novel catalyst existed as an aqueous suspension.

AB - In this study, a novel catalyst based on hydroxyapatite doped by cobalt for chemiluminescence reaction of luminol oxidation by H2O2 was suggested for the first time. The catalyst nanoparticles were synthesized by a hydrothermal method and characterized by various methods including density functional theory calculations. The impact of nanoparticles sizes, surface composition, contact efficiency and crystallinity on chemiluminescence intensity were investigated. The maximum chemiluminescence intensity was obtained for polycrystalline nanoparticles. This phenomenon was studied in detail and applied for chemiluminescence analysis for the first time. The chemiluminescence determination of sulfonamides as model analytes was considered. The sensing was based on sulfonamides-dependent quenching of the chemiluminescence intensity in the presence of novel catalyst existed as an aqueous suspension.

KW - Catalysis

KW - Chemiluminescence

KW - Crystal parameters

KW - Hydroxyapatite nanoparticles

KW - Polycrystalline nanoparticles

KW - Sulfonamides

KW - SULFONAMIDES

UR - http://www.scopus.com/inward/record.url?scp=85083817285&partnerID=8YFLogxK

U2 - 10.1016/j.saa.2020.118382

DO - 10.1016/j.saa.2020.118382

M3 - Article

C2 - 32361517

AN - SCOPUS:85083817285

VL - 237

JO - SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY

JF - SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY

SN - 1386-1425

M1 - 118382

ER -

ID: 61163600