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Cluster quantum chemical study of the Grignard Reagent formation. / Tulub, A. V.; Porsev, V. V.

SelfOrganization of Molecular Systems: From Molecules and Clusters to Nanotubes and Proteins. ed. / Nino Russo; Victor Ya Antonchenko; Eugene Kryachko. Springer Nature, 2009. p. 385-397 (NATO Science for Peace and Security Series A: Chemistry and Biology).

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review

Harvard

Tulub, AV & Porsev, VV 2009, Cluster quantum chemical study of the Grignard Reagent formation. in N Russo, VY Antonchenko & E Kryachko (eds), SelfOrganization of Molecular Systems: From Molecules and Clusters to Nanotubes and Proteins. NATO Science for Peace and Security Series A: Chemistry and Biology, Springer Nature, pp. 385-397. https://doi.org/10.1007/978-90-481-2590-6_18

APA

Tulub, A. V., & Porsev, V. V. (2009). Cluster quantum chemical study of the Grignard Reagent formation. In N. Russo, V. Y. Antonchenko, & E. Kryachko (Eds.), SelfOrganization of Molecular Systems: From Molecules and Clusters to Nanotubes and Proteins (pp. 385-397). (NATO Science for Peace and Security Series A: Chemistry and Biology). Springer Nature. https://doi.org/10.1007/978-90-481-2590-6_18

Vancouver

Tulub AV, Porsev VV. Cluster quantum chemical study of the Grignard Reagent formation. In Russo N, Antonchenko VY, Kryachko E, editors, SelfOrganization of Molecular Systems: From Molecules and Clusters to Nanotubes and Proteins. Springer Nature. 2009. p. 385-397. (NATO Science for Peace and Security Series A: Chemistry and Biology). https://doi.org/10.1007/978-90-481-2590-6_18

Author

Tulub, A. V. ; Porsev, V. V. / Cluster quantum chemical study of the Grignard Reagent formation. SelfOrganization of Molecular Systems: From Molecules and Clusters to Nanotubes and Proteins. editor / Nino Russo ; Victor Ya Antonchenko ; Eugene Kryachko. Springer Nature, 2009. pp. 385-397 (NATO Science for Peace and Security Series A: Chemistry and Biology).

BibTeX

@inbook{e5b0fa79523246e893fbaead9f72b1da,
title = "Cluster quantum chemical study of the Grignard Reagent formation",
abstract = "The main stages of the Grignard reagent formation are described in a framework of quantum chemical cluster model. We have established two kinds of the adsorption of CH3 Hal on Mgn clusters, one of which leads to radical formation and the second is responsible for radical free dissociate adsorption. The charge redistribution in cluster CH3 Mgn Hal result to the strong electrostatic interaction with ether and Grignard reagent formation without any activation barrier.",
keywords = "Grignard reagent formation, Magnesium clusters, Quantum chemical study",
author = "Tulub, {A. V.} and Porsev, {V. V.}",
year = "2009",
doi = "10.1007/978-90-481-2590-6_18",
language = "English",
isbn = "9789048124831",
series = "NATO Science for Peace and Security Series A: Chemistry and Biology",
publisher = "Springer Nature",
pages = "385--397",
editor = "Nino Russo and Antonchenko, {Victor Ya} and Eugene Kryachko",
booktitle = "SelfOrganization of Molecular Systems",
address = "Germany",

}

RIS

TY - CHAP

T1 - Cluster quantum chemical study of the Grignard Reagent formation

AU - Tulub, A. V.

AU - Porsev, V. V.

PY - 2009

Y1 - 2009

N2 - The main stages of the Grignard reagent formation are described in a framework of quantum chemical cluster model. We have established two kinds of the adsorption of CH3 Hal on Mgn clusters, one of which leads to radical formation and the second is responsible for radical free dissociate adsorption. The charge redistribution in cluster CH3 Mgn Hal result to the strong electrostatic interaction with ether and Grignard reagent formation without any activation barrier.

AB - The main stages of the Grignard reagent formation are described in a framework of quantum chemical cluster model. We have established two kinds of the adsorption of CH3 Hal on Mgn clusters, one of which leads to radical formation and the second is responsible for radical free dissociate adsorption. The charge redistribution in cluster CH3 Mgn Hal result to the strong electrostatic interaction with ether and Grignard reagent formation without any activation barrier.

KW - Grignard reagent formation

KW - Magnesium clusters

KW - Quantum chemical study

UR - http://www.scopus.com/inward/record.url?scp=67649746260&partnerID=8YFLogxK

U2 - 10.1007/978-90-481-2590-6_18

DO - 10.1007/978-90-481-2590-6_18

M3 - Chapter

SN - 9789048124831

T3 - NATO Science for Peace and Security Series A: Chemistry and Biology

SP - 385

EP - 397

BT - SelfOrganization of Molecular Systems

A2 - Russo, Nino

A2 - Antonchenko, Victor Ya

A2 - Kryachko, Eugene

PB - Springer Nature

ER -

ID: 4553266