Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review
The main stages of the Grignard reagent formation are described in a framework of quantum chemical cluster model. We have established two kinds of the adsorption of CH3 Hal on Mgn clusters, one of which leads to radical formation and the second is responsible for radical free dissociate adsorption. The charge redistribution in cluster CH3 Mgn Hal result to the strong electrostatic interaction with ether and Grignard reagent formation without any activation barrier.
Original language | English |
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Title of host publication | SelfOrganization of Molecular Systems |
Subtitle of host publication | From Molecules and Clusters to Nanotubes and Proteins |
Editors | Nino Russo, Victor Ya Antonchenko, Eugene Kryachko |
Publisher | Springer Nature |
Pages | 385-397 |
Number of pages | 13 |
ISBN (Electronic) | 978-90-481-2590-6 |
ISBN (Print) | 9789048124831 |
DOIs | |
State | Published - 2009 |
Name | NATO Science for Peace and Security Series A: Chemistry and Biology |
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ISSN (Print) | 1874-6489 |
ID: 4553266