Chromatographic characteristics of α-alkynols

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Chromatographic characteristics of α-alkynols. / Artsybasheva, Yu.P.; Zenkevich, I.G.

In: Russian Journal of General Chemistry, Vol. 84, No. 3, 2014, p. 449-456.

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Author

Artsybasheva, Yu.P. ; Zenkevich, I.G. / Chromatographic characteristics of α-alkynols. In: Russian Journal of General Chemistry. 2014 ; Vol. 84, No. 3. pp. 449-456.

BibTeX

@article{f9994f192f4d4da287d5e3765f00eece,

title = "Chromatographic characteristics of α-alkynols",

abstract = "Chromatographic retention indices on a standard nonpolar poly(dimethylsiloxane) phase were determined for 33 α-alkynols and their 27 dehydration products (conjugated alkenynes). The resulting data are proposed to be verified using the retention indices of acetylenic alcohols estimated by the additive scheme from the retention indices of isostructural alkynes with the inclusion of increments for secondary and tertiary hydroxy groups. The analogous approach to data the verification of data for alkenynes is based on correlation of their retention indices with normal boiling points. {\textcopyright} 2014 Pleiades Publishing, Ltd.",

author = "Yu.P. Artsybasheva and I.G. Zenkevich",

year = "2014",

doi = "10.1134/S1070363214030074",

language = "English",

volume = "84",

pages = "449--456",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "3",

}

RIS

TY - JOUR

T1 - Chromatographic characteristics of α-alkynols

AU - Artsybasheva, Yu.P.

AU - Zenkevich, I.G.

PY - 2014

Y1 - 2014

N2 - Chromatographic retention indices on a standard nonpolar poly(dimethylsiloxane) phase were determined for 33 α-alkynols and their 27 dehydration products (conjugated alkenynes). The resulting data are proposed to be verified using the retention indices of acetylenic alcohols estimated by the additive scheme from the retention indices of isostructural alkynes with the inclusion of increments for secondary and tertiary hydroxy groups. The analogous approach to data the verification of data for alkenynes is based on correlation of their retention indices with normal boiling points. © 2014 Pleiades Publishing, Ltd.

AB - Chromatographic retention indices on a standard nonpolar poly(dimethylsiloxane) phase were determined for 33 α-alkynols and their 27 dehydration products (conjugated alkenynes). The resulting data are proposed to be verified using the retention indices of acetylenic alcohols estimated by the additive scheme from the retention indices of isostructural alkynes with the inclusion of increments for secondary and tertiary hydroxy groups. The analogous approach to data the verification of data for alkenynes is based on correlation of their retention indices with normal boiling points. © 2014 Pleiades Publishing, Ltd.

U2 - 10.1134/S1070363214030074

DO - 10.1134/S1070363214030074

M3 - Article

VL - 84

SP - 449

EP - 456

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 3

ER -

ID: 7035361