Research output: Contribution to journal › Article › peer-review
Binuclear manganese(II) complexes based on pyridyl-containing dialkylphosphine oxides. / Enikeeva, Kamila R.; Shamsieva, Aliia V.; Kasimov, Airat I.; Fayzullin, Robert R.; Litvinov, Igor A.; Khrizanforova, Vera V.; Budnikova, Yulia H.; Lyubina, Anna P.; Voloshina, Alexandra D.; Колесников, Илья Евгеньевич; Musina, Elvira I.; Karasik, Andrey A.
In: Inorganica Chimica Acta, Vol. 558, 121741, 01.12.2023.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Binuclear manganese(II) complexes based on pyridyl-containing dialkylphosphine oxides
AU - Enikeeva, Kamila R.
AU - Shamsieva, Aliia V.
AU - Kasimov, Airat I.
AU - Fayzullin, Robert R.
AU - Litvinov, Igor A.
AU - Khrizanforova, Vera V.
AU - Budnikova, Yulia H.
AU - Lyubina, Anna P.
AU - Voloshina, Alexandra D.
AU - Колесников, Илья Евгеньевич
AU - Musina, Elvira I.
AU - Karasik, Andrey A.
PY - 2023/12/1
Y1 - 2023/12/1
N2 - New manganese(II) complexes with Mn2Cl2 and more rare Mn2O2 cores were obtained based on the diisopropyl(pyridin-2-yl)phosphine oxide (L2) and diethyl(pyridin-2-yl)phosphine oxide (L3). The crystal structures and sample purity of the compounds were determined by single-crystal and powder X-ray diffraction. The luminescence, the electrocatalytic activity in hydrogen evolution reaction, and the cytotoxicity against the M−HeLa and HuTu80 cancer cell lines and Chang liver normal cell lines were investigated. It was found that manganese(II) complex 3 with the Mn2O2 core was the effective catalyst in the hydrogen evolution reaction and exhibited high cytotoxicity against the cancer HuTu80 cell line.
AB - New manganese(II) complexes with Mn2Cl2 and more rare Mn2O2 cores were obtained based on the diisopropyl(pyridin-2-yl)phosphine oxide (L2) and diethyl(pyridin-2-yl)phosphine oxide (L3). The crystal structures and sample purity of the compounds were determined by single-crystal and powder X-ray diffraction. The luminescence, the electrocatalytic activity in hydrogen evolution reaction, and the cytotoxicity against the M−HeLa and HuTu80 cancer cell lines and Chang liver normal cell lines were investigated. It was found that manganese(II) complex 3 with the Mn2O2 core was the effective catalyst in the hydrogen evolution reaction and exhibited high cytotoxicity against the cancer HuTu80 cell line.
KW - Cytotoxicity
KW - Electrochemistry
KW - N, O-chelating ligands
KW - Tertiary phosphine oxides
KW - X-ray structure
KW - manganese(II) complexes
UR - https://www.mendeley.com/catalogue/3c66167c-8f45-3897-a19e-3d1a3966b2d6/
U2 - 10.1016/j.ica.2023.121741
DO - 10.1016/j.ica.2023.121741
M3 - статья
VL - 558
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
M1 - 121741
ER -
ID: 114271950