Binuclear and polymeric bromobismuthate complexes

Binuclear and polymeric bromobismuthate complexes: Crystal structures and thermal stability

Research output: Contribution to journal › Article › peer-review

Institute of Chemistry

DOI

https://doi.org/10.1016/j.poly.2018.12.017
Final published version

Sergey A. Adonin
Igor D. Gorokh
Denis G. Samsonenko
Alexander S. Novikov
Ilya V. Korolkov
Pavel E. Plyusnin
Maxim N. Sokolov
Vladimir P. Fedin

A series of nine bromobismuthate complexes containing Py-derived cations – (cat)₃[Bi₂Br₉] (cat = 1-i-PrPy (1), 3,5-MePyH (2), 1,2-MePy (3), 1,3-MePy (4), 1-Et-3-MePy (5), 1-Et-4-MePy (6), 1,2,4,6-MePy (7)), (2-MePyH){[BiBr₄]} (8) and (1-Bz-4-MePy)₄[Bi₂Br₁₀] (9) were prepared and characterized by X-ray diffractometry. Thermal stability was studied for synthesized compounds, as well as for the related complexes reported earlier.

Original language	English
Pages (from-to)	318-322
Number of pages	5
Journal	Polyhedron
Volume	159
Early online date	18 Dec 2018
DOIs	https://doi.org/10.1016/j.poly.2018.12.017
State	Published - 1 Feb 2019

Scopus subject areas

Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry

Research areas

Bismuth, Crystal structure, Halide complexes, Halometalate, Hirshfeld surface analysis, BI(III), BISMUTH COMPLEXES, CATIONS, BIDENTATE BASE SYSTEMS, DIVERSITY, BROMIDE, HYBRID, CHLORIDE

ID: 37308778