Standard

Bi2O2SO4, a new representative of the grandreefite structure type. / Charkin, D. O.; Akimov, G. A.; Plokhikh, I. V.; Zaloga, A. N.; Borisov, A. S.; Stefanovich, S. Yu; Kuznetsov, A. N.; Siidra, O. I.

In: Journal of Solid State Chemistry, Vol. 282, 121124, 02.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Charkin, DO, Akimov, GA, Plokhikh, IV, Zaloga, AN, Borisov, AS, Stefanovich, SY, Kuznetsov, AN & Siidra, OI 2020, 'Bi2O2SO4, a new representative of the grandreefite structure type', Journal of Solid State Chemistry, vol. 282, 121124. https://doi.org/10.1016/j.jssc.2019.121124

APA

Charkin, D. O., Akimov, G. A., Plokhikh, I. V., Zaloga, A. N., Borisov, A. S., Stefanovich, S. Y., Kuznetsov, A. N., & Siidra, O. I. (2020). Bi2O2SO4, a new representative of the grandreefite structure type. Journal of Solid State Chemistry, 282, [121124]. https://doi.org/10.1016/j.jssc.2019.121124

Vancouver

Charkin DO, Akimov GA, Plokhikh IV, Zaloga AN, Borisov AS, Stefanovich SY et al. Bi2O2SO4, a new representative of the grandreefite structure type. Journal of Solid State Chemistry. 2020 Feb;282. 121124. https://doi.org/10.1016/j.jssc.2019.121124

Author

Charkin, D. O. ; Akimov, G. A. ; Plokhikh, I. V. ; Zaloga, A. N. ; Borisov, A. S. ; Stefanovich, S. Yu ; Kuznetsov, A. N. ; Siidra, O. I. / Bi2O2SO4, a new representative of the grandreefite structure type. In: Journal of Solid State Chemistry. 2020 ; Vol. 282.

BibTeX

@article{8707ce4df43f4206a4a2b9ef35f738b9,
title = "Bi2O2SO4, a new representative of the grandreefite structure type",
abstract = "Single-phase polycrystalline bismuth oxysulfate, Bi2O2SO4, has been prepared via low-temperature reaction between Bi2O2CO3 and (NH4)2SO4. The compound is monoclinic (C2/m, a ​= ​14.1659(4) {\AA}, b ​= ​4.2344(1) {\AA}, c ​= ​8.2100(2) {\AA}, β ​= ​106.7201(8)°, V ​= ​471.65(2) {\AA}3) and isostructural to isoelectronic Pb2F2SO4 and to isolobal Ln2O2SO4. Upon heating, it decomposes at ~550 ​°C into the Bi28O32(SO4)10 which is stable until ~775 ​°C. DFT calculations predict it to be a wide-gap semiconductor.",
keywords = "Bismuth oxysulfate, Crystal structure, Electronic structure, Thermal properties",
author = "Charkin, {D. O.} and Akimov, {G. A.} and Plokhikh, {I. V.} and Zaloga, {A. N.} and Borisov, {A. S.} and Stefanovich, {S. Yu} and Kuznetsov, {A. N.} and Siidra, {O. I.}",
year = "2020",
month = feb,
doi = "10.1016/j.jssc.2019.121124",
language = "English",
volume = "282",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Bi2O2SO4, a new representative of the grandreefite structure type

AU - Charkin, D. O.

AU - Akimov, G. A.

AU - Plokhikh, I. V.

AU - Zaloga, A. N.

AU - Borisov, A. S.

AU - Stefanovich, S. Yu

AU - Kuznetsov, A. N.

AU - Siidra, O. I.

PY - 2020/2

Y1 - 2020/2

N2 - Single-phase polycrystalline bismuth oxysulfate, Bi2O2SO4, has been prepared via low-temperature reaction between Bi2O2CO3 and (NH4)2SO4. The compound is monoclinic (C2/m, a ​= ​14.1659(4) Å, b ​= ​4.2344(1) Å, c ​= ​8.2100(2) Å, β ​= ​106.7201(8)°, V ​= ​471.65(2) Å3) and isostructural to isoelectronic Pb2F2SO4 and to isolobal Ln2O2SO4. Upon heating, it decomposes at ~550 ​°C into the Bi28O32(SO4)10 which is stable until ~775 ​°C. DFT calculations predict it to be a wide-gap semiconductor.

AB - Single-phase polycrystalline bismuth oxysulfate, Bi2O2SO4, has been prepared via low-temperature reaction between Bi2O2CO3 and (NH4)2SO4. The compound is monoclinic (C2/m, a ​= ​14.1659(4) Å, b ​= ​4.2344(1) Å, c ​= ​8.2100(2) Å, β ​= ​106.7201(8)°, V ​= ​471.65(2) Å3) and isostructural to isoelectronic Pb2F2SO4 and to isolobal Ln2O2SO4. Upon heating, it decomposes at ~550 ​°C into the Bi28O32(SO4)10 which is stable until ~775 ​°C. DFT calculations predict it to be a wide-gap semiconductor.

KW - Bismuth oxysulfate

KW - Crystal structure

KW - Electronic structure

KW - Thermal properties

UR - http://www.scopus.com/inward/record.url?scp=85076534742&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2019.121124

DO - 10.1016/j.jssc.2019.121124

M3 - Article

AN - SCOPUS:85076534742

VL - 282

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

M1 - 121124

ER -

ID: 53747457