Arsenic contamination of coarse-grained and nanostructured nitinol surfaces induced by chemical treatment in hydrofluoric acid. / Korotin, D. M.; Bartkowski, S.; Kurmaev, E. Z.; Borchers, C.; Müller, M.; Neumann, M.; Gunderov, D. V.; Valiev, R. Z.; Cholakh, S. O.
In: Journal of Biomedical Materials Research - Part B Applied Biomaterials, Vol. 100 B, No. 7, 01.10.2012, p. 1812-1816.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Arsenic contamination of coarse-grained and nanostructured nitinol surfaces induced by chemical treatment in hydrofluoric acid
AU - Korotin, D. M.
AU - Bartkowski, S.
AU - Kurmaev, E. Z.
AU - Borchers, C.
AU - Müller, M.
AU - Neumann, M.
AU - Gunderov, D. V.
AU - Valiev, R. Z.
AU - Cholakh, S. O.
PY - 2012/10/1
Y1 - 2012/10/1
N2 - XPS measurements of coarse-grained and nanostructured nitinol (Ni 50.2Ti49.8) before and after chemical treatment in hydrofluoric acid (40% HF, 1 min) are presented. The nanostructured state, providing the excellent mechanical properties of nitinol, is achieved by severe plastic deformation. The near-surface layers of nitinol were studied by XPS depth profiling. According to the obtained results, a chemical treatment in hydrofluoric acid reduces the thickness of the protective TiO2 oxide layer and induces a nickel release from the nitinol surface and an arsenic contamination, and can therefore not be recommended as conditioning to increase the roughness of NiTi-implants. A detailed evaluation of the resulting toxicological risks is given. © 2012 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 2012.
AB - XPS measurements of coarse-grained and nanostructured nitinol (Ni 50.2Ti49.8) before and after chemical treatment in hydrofluoric acid (40% HF, 1 min) are presented. The nanostructured state, providing the excellent mechanical properties of nitinol, is achieved by severe plastic deformation. The near-surface layers of nitinol were studied by XPS depth profiling. According to the obtained results, a chemical treatment in hydrofluoric acid reduces the thickness of the protective TiO2 oxide layer and induces a nickel release from the nitinol surface and an arsenic contamination, and can therefore not be recommended as conditioning to increase the roughness of NiTi-implants. A detailed evaluation of the resulting toxicological risks is given. © 2012 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 2012.
KW - arsenic contamination
KW - nitinol
KW - TiO
KW - XPS
UR - http://www.scopus.com/inward/record.url?scp=84865963848&partnerID=8YFLogxK
U2 - 10.1002/jbm.b.32748
DO - 10.1002/jbm.b.32748
M3 - Article
C2 - 22807469
AN - SCOPUS:84865963848
VL - 100 B
SP - 1812
EP - 1816
JO - Journal of Biomedical Materials Research - Part B Applied Biomaterials
JF - Journal of Biomedical Materials Research - Part B Applied Biomaterials
SN - 1552-4973
IS - 7
ER -
ID: 35166922