Research output: Contribution to journal › Article › peer-review
Al 3+ solvation in solutions of aluminum nitrate in a protic ionic liquid : Nuclear magnetic resonance verification of the solvation shell composition. / Матвеев, Владимир Викторович; Иевлев, Александр Вячеславович; Šoltésová, Mária; Štěpánková, Helena; Lähderanta, Erkki; Varela, Luis Miguel.
In: Magnetic Resonance in Chemistry, Vol. 60, No. 2, 02.2022, p. 221-225.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Al 3+ solvation in solutions of aluminum nitrate in a protic ionic liquid
T2 - Nuclear magnetic resonance verification of the solvation shell composition
AU - Матвеев, Владимир Викторович
AU - Иевлев, Александр Вячеславович
AU - Šoltésová, Mária
AU - Štěpánková, Helena
AU - Lähderanta, Erkki
AU - Varela, Luis Miguel
N1 - Publisher Copyright: © 2021 John Wiley & Sons, Ltd.
PY - 2022/2
Y1 - 2022/2
N2 - The closest environment of Al3+ cations was analyzed in detail in solutions of aluminum nitrate in the prototypical protic ionic liquid ethyl ammonium nitrate (EAN) using 1H and 14N nuclear magnetic resonance (NMR) spectra. For Al (NO3)3–EAN mixtures with different water content, a quantitative analysis of the integral intensities of the 1H and 14N signals was carried out and the composition of the first solvation shell of the aluminum cation was refined.
AB - The closest environment of Al3+ cations was analyzed in detail in solutions of aluminum nitrate in the prototypical protic ionic liquid ethyl ammonium nitrate (EAN) using 1H and 14N nuclear magnetic resonance (NMR) spectra. For Al (NO3)3–EAN mixtures with different water content, a quantitative analysis of the integral intensities of the 1H and 14N signals was carried out and the composition of the first solvation shell of the aluminum cation was refined.
KW - 1H
KW - 14N
KW - 27Al
KW - aqua complex
KW - ionic liquid
KW - NMR
KW - solvation shell
KW - H
KW - Al
KW - N
KW - Al-27
KW - NUMBER
KW - N-14
KW - PERCHLORATE
KW - ELECTROLYTES
KW - H-1
KW - MIXTURES
KW - DYNAMICS
KW - WATER
UR - http://www.scopus.com/inward/record.url?scp=85116475327&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/8245ad2c-6c06-3951-b5e7-bb1f363638a1/
U2 - 10.1002/mrc.5220
DO - 10.1002/mrc.5220
M3 - Article
VL - 60
SP - 221
EP - 225
JO - Magnetic Resonance in Chemistry
JF - Magnetic Resonance in Chemistry
SN - 0749-1581
IS - 2
ER -
ID: 85937485