Research output: Contribution to journal › Article › peer-review
Adsorption voltammetric peak: Approximate calculation algorithm taking into account lateral interactions. / Ivanov, Vladimir D. .
In: Journal of Solid State Electrochemistry, Vol. 23, No. 5, 05.2019, p. 1371–1377.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Adsorption voltammetric peak: Approximate calculation algorithm taking into account lateral interactions
AU - Ivanov, Vladimir D.
N1 - Ivanov. V.D. Adsorption voltammetric peak: Approximate calculation algorithm taking into account lateral interactions / V.D. Ivanov // Journal of Solid State Electrochemistry. - 2019 - V. 23 - P. 1371–1377.
PY - 2019/5
Y1 - 2019/5
N2 - Voltammetric peak of adsorbed electroactive system with lateral interactions may be described theoretically by a parametric equation; no exact explicit current-potential relation is achievable. Approximate calculation algorithm (LAT) is presented for establishing this relation; separate version of algorithm (LAT1) has been developed for negative values of the interaction parameter. These algorithms allow performing calculations with high accuracy. Unfortunately, precision has been achieved at the expense of simplicity: LAT makes use of up to nine adjustable coefficients. Accuracy of LAT has been compared with accuracy of GLI equation proposed by Alévêque and Levillain Electrochem Commun 67:73–79, 2016.
AB - Voltammetric peak of adsorbed electroactive system with lateral interactions may be described theoretically by a parametric equation; no exact explicit current-potential relation is achievable. Approximate calculation algorithm (LAT) is presented for establishing this relation; separate version of algorithm (LAT1) has been developed for negative values of the interaction parameter. These algorithms allow performing calculations with high accuracy. Unfortunately, precision has been achieved at the expense of simplicity: LAT makes use of up to nine adjustable coefficients. Accuracy of LAT has been compared with accuracy of GLI equation proposed by Alévêque and Levillain Electrochem Commun 67:73–79, 2016.
KW - вольтамперометрия
KW - адсорбционный пик
KW - моделирование
KW - voltammetry
KW - adsorption
KW - interaction
KW - Adsorption
KW - Lateral interactions
KW - Voltammetry
KW - Modelling
UR - http://www.scopus.com/inward/record.url?scp=85062971604&partnerID=8YFLogxK
UR - https://link.springer.com/journal/10008/23/5
U2 - 10.1007/s10008-019-04235-3
DO - 10.1007/s10008-019-04235-3
M3 - Article
VL - 23
SP - 1371
EP - 1377
JO - Journal of Solid State Electrochemistry
JF - Journal of Solid State Electrochemistry
SN - 1432-8488
IS - 5
ER -
ID: 39957841