• Vladimir D. Ivanov
Voltammetric peak of adsorbed electroactive system with lateral interactions may be described theoretically by a parametric equation; no exact explicit current-potential relation is achievable. Approximate calculation algorithm (LAT) is presented for establishing this relation; separate version of algorithm (LAT1) has been developed for negative values of the interaction parameter. These algorithms allow performing calculations with high accuracy. Unfortunately, precision has been achieved at the expense of simplicity: LAT makes use of up to nine adjustable coefficients. Accuracy of LAT has been compared with accuracy of GLI equation proposed by Alévêque and Levillain Electrochem Commun 67:73–79, 2016.
Translated title of the contributionАдсорбционный пик на вольтамперограмме: Приближенный расчет с учетом взаимодействий в адсорбционном слое
Original languageEnglish
Pages (from-to)1371–1377
JournalJournal of Solid State Electrochemistry
Volume23
Issue number5
DOIs
StatePublished - May 2019

    Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Electrical and Electronic Engineering
  • Electrochemistry

    Research areas

  • voltammetry, adsorption, interaction, Adsorption, Lateral interactions, Voltammetry, Modelling

ID: 39957841