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A convenient route to mixed cationic group 13/14/15 compounds. / Ackermann, Matthias T.; Seidl, Michael; Grande, Riccardo; Zhou, Yuqiao ; Ferguson, Michael J. ; Тимошкин, Алексей Юрьевич; Rivard, Eric; Scheer, Manfred.

In: Chemical Science, Vol. 14, No. 9, 01.03.2023, p. 2313-2317.

Research output: Contribution to journal › Article › peer-review

Harvard

Ackermann, MT, Seidl, M, Grande, R, Zhou, Y, Ferguson, MJ, Тимошкин, АЮ, Rivard, E & Scheer, M 2023, 'A convenient route to mixed cationic group 13/14/15 compounds', Chemical Science, vol. 14, no. 9, pp. 2313-2317. https://doi.org/10.1039/D2SC06594K

APA

Ackermann, M. T., Seidl, M., Grande, R., Zhou, Y., Ferguson, M. J., Тимошкин, А. Ю., Rivard, E., & Scheer, M. (2023). A convenient route to mixed cationic group 13/14/15 compounds. Chemical Science, 14(9), 2313-2317. https://doi.org/10.1039/D2SC06594K

Vancouver

Ackermann MT, Seidl M, Grande R, Zhou Y, Ferguson MJ, Тимошкин АЮ et al. A convenient route to mixed cationic group 13/14/15 compounds. Chemical Science. 2023 Mar 1;14(9):2313-2317. https://doi.org/10.1039/D2SC06594K

Author

Ackermann, Matthias T. ; Seidl, Michael ; Grande, Riccardo ; Zhou, Yuqiao ; Ferguson, Michael J. ; Тимошкин, Алексей Юрьевич ; Rivard, Eric ; Scheer, Manfred. / A convenient route to mixed cationic group 13/14/15 compounds. In: Chemical Science. 2023 ; Vol. 14, No. 9. pp. 2313-2317.

BibTeX

@article{7fab2f1569bb4b23aa6c3ccbae09390a,
title = "A convenient route to mixed cationic group 13/14/15 compounds",
abstract = "The formation of novel cationic mixed main group compounds is reported revealing a chain composed of different elements of group 13, 14, and 15. Reactions of different pnictogenylboranes R2EBH2$NMe3 (E = P, R = Ph, H; E = As, R = Ph, H) with the NHC-stabilized compound IDipp$GeH2BH2OTf (1) (IDipp = 1,3- bis(2,6-diisopropylphenyl)imidazole-2-ylidene) were carried out, yielding the novel cationic, mixed group 13/14/15 compounds [IDipp$GeH2BH2ER2BH2$NMe3]+ (2a E = P; R = Ph; 2b E = As; R = Ph; 3a E = P; R = H; 3b E = As; R = H) by the nucleophilic substitution of the triflate (OTf) group. The products were analysed by NMR spectroscopy and mass spectrometry and for 2a and 2b also by X-ray structure analysis. Further reactions of 1 with H2EBH2$IDipp (E = P, As) resulted in the unprecedented parent complexes [IDipp$GeH2BH2EH2BH2$IDipp][OTf] (5a E = P; 5b E = As), which were studied by X-ray structure analysis, NMR spectroscopy and mass spectrometry. Accompanying DFT computations give insight into the stability of the formed products with respect to their decomposition.",
author = "Ackermann, {Matthias T.} and Michael Seidl and Riccardo Grande and Yuqiao Zhou and Ferguson, {Michael J.} and Тимошкин, {Алексей Юрьевич} and Eric Rivard and Manfred Scheer",
year = "2023",
month = mar,
day = "1",
doi = "10.1039/D2SC06594K",
language = "English",
volume = "14",
pages = "2313--2317",
journal = "Chemical Science",
issn = "2041-6520",
publisher = "Royal Society of Chemistry",
number = "9",

}

RIS

TY - JOUR

T1 - A convenient route to mixed cationic group 13/14/15 compounds

AU - Ackermann, Matthias T.

AU - Seidl, Michael

AU - Grande, Riccardo

AU - Zhou, Yuqiao

AU - Ferguson, Michael J.

AU - Тимошкин, Алексей Юрьевич

AU - Rivard, Eric

AU - Scheer, Manfred

PY - 2023/3/1

Y1 - 2023/3/1

N2 - The formation of novel cationic mixed main group compounds is reported revealing a chain composed of different elements of group 13, 14, and 15. Reactions of different pnictogenylboranes R2EBH2$NMe3 (E = P, R = Ph, H; E = As, R = Ph, H) with the NHC-stabilized compound IDipp$GeH2BH2OTf (1) (IDipp = 1,3- bis(2,6-diisopropylphenyl)imidazole-2-ylidene) were carried out, yielding the novel cationic, mixed group 13/14/15 compounds [IDipp$GeH2BH2ER2BH2$NMe3]+ (2a E = P; R = Ph; 2b E = As; R = Ph; 3a E = P; R = H; 3b E = As; R = H) by the nucleophilic substitution of the triflate (OTf) group. The products were analysed by NMR spectroscopy and mass spectrometry and for 2a and 2b also by X-ray structure analysis. Further reactions of 1 with H2EBH2$IDipp (E = P, As) resulted in the unprecedented parent complexes [IDipp$GeH2BH2EH2BH2$IDipp][OTf] (5a E = P; 5b E = As), which were studied by X-ray structure analysis, NMR spectroscopy and mass spectrometry. Accompanying DFT computations give insight into the stability of the formed products with respect to their decomposition.

AB - The formation of novel cationic mixed main group compounds is reported revealing a chain composed of different elements of group 13, 14, and 15. Reactions of different pnictogenylboranes R2EBH2$NMe3 (E = P, R = Ph, H; E = As, R = Ph, H) with the NHC-stabilized compound IDipp$GeH2BH2OTf (1) (IDipp = 1,3- bis(2,6-diisopropylphenyl)imidazole-2-ylidene) were carried out, yielding the novel cationic, mixed group 13/14/15 compounds [IDipp$GeH2BH2ER2BH2$NMe3]+ (2a E = P; R = Ph; 2b E = As; R = Ph; 3a E = P; R = H; 3b E = As; R = H) by the nucleophilic substitution of the triflate (OTf) group. The products were analysed by NMR spectroscopy and mass spectrometry and for 2a and 2b also by X-ray structure analysis. Further reactions of 1 with H2EBH2$IDipp (E = P, As) resulted in the unprecedented parent complexes [IDipp$GeH2BH2EH2BH2$IDipp][OTf] (5a E = P; 5b E = As), which were studied by X-ray structure analysis, NMR spectroscopy and mass spectrometry. Accompanying DFT computations give insight into the stability of the formed products with respect to their decomposition.

UR - https://pubs.rsc.org/en/content/articlelanding/2023/SC/D2SC06594K

UR - https://www.mendeley.com/catalogue/bbf70cf9-0703-331a-89c4-a5a4e5dbcfa7/

U2 - 10.1039/D2SC06594K

DO - 10.1039/D2SC06594K

M3 - Article

C2 - 36873855

VL - 14

SP - 2313

EP - 2317

JO - Chemical Science

JF - Chemical Science

SN - 2041-6520

IS - 9

ER -

ID: 103367123