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“2+1B” Technetium-99m Tricarbonyl Complexes with N,N'-Bidentate Ligands and Methyl 14-Isocyano-3-methyltetradecanoate. / Мирославов, Александр Евгеньевич; Кузьменко, Пётр Михайлович; Тюпина, Маргарита Юрьевна; Сахоненкова, Анна Павловна; Сидоренко, Георгий Васильевич; Кочергина, Анастасия Романовна; Кротов, Сергей Алексеевич.

In: Radiochemistry, Vol. 66, No. 4, 01.08.2024, p. 521–529.

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@article{491b6dbd09ab49c4a336868e04451597,
title = "“2+1B” Technetium-99m Tricarbonyl Complexes with N,N'-Bidentate Ligands and Methyl 14-Isocyano-3-methyltetradecanoate",
abstract = "A novel 12-step procedure was developed for preparing methyl 14-isocyano-3-methyltetradecanoate. “2+1B” tricarbonyl complexes [99mTc(CO)3(N^N)CN(CH2)11CH(CH3)CH2COOMe]+, where N^N = 2,2'-bipyridine(bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [99mTc(CO)3(N^N)(H2O,EtOH)]+ withmethyl 14-isocyano-3-methyltetradecanoate in aqueous ethanol. The formation of technetium-99m complexeswas confi rmed by HPLC, and the partition coeffi cient (n-octanol/water) of these complexes was measured.",
author = "Мирославов, {Александр Евгеньевич} and Кузьменко, {Пётр Михайлович} and Тюпина, {Маргарита Юрьевна} and Сахоненкова, {Анна Павловна} and Сидоренко, {Георгий Васильевич} and Кочергина, {Анастасия Романовна} and Кротов, {Сергей Алексеевич}",
year = "2024",
month = aug,
day = "1",
doi = "10.1134/s1066362224040143",
language = "English",
volume = "66",
pages = "521–529",
journal = "Radiochemistry",
issn = "1066-3622",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - “2+1B” Technetium-99m Tricarbonyl Complexes with N,N'-Bidentate Ligands and Methyl 14-Isocyano-3-methyltetradecanoate

AU - Мирославов, Александр Евгеньевич

AU - Кузьменко, Пётр Михайлович

AU - Тюпина, Маргарита Юрьевна

AU - Сахоненкова, Анна Павловна

AU - Сидоренко, Георгий Васильевич

AU - Кочергина, Анастасия Романовна

AU - Кротов, Сергей Алексеевич

PY - 2024/8/1

Y1 - 2024/8/1

N2 - A novel 12-step procedure was developed for preparing methyl 14-isocyano-3-methyltetradecanoate. “2+1B” tricarbonyl complexes [99mTc(CO)3(N^N)CN(CH2)11CH(CH3)CH2COOMe]+, where N^N = 2,2'-bipyridine(bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [99mTc(CO)3(N^N)(H2O,EtOH)]+ withmethyl 14-isocyano-3-methyltetradecanoate in aqueous ethanol. The formation of technetium-99m complexeswas confi rmed by HPLC, and the partition coeffi cient (n-octanol/water) of these complexes was measured.

AB - A novel 12-step procedure was developed for preparing methyl 14-isocyano-3-methyltetradecanoate. “2+1B” tricarbonyl complexes [99mTc(CO)3(N^N)CN(CH2)11CH(CH3)CH2COOMe]+, where N^N = 2,2'-bipyridine(bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [99mTc(CO)3(N^N)(H2O,EtOH)]+ withmethyl 14-isocyano-3-methyltetradecanoate in aqueous ethanol. The formation of technetium-99m complexeswas confi rmed by HPLC, and the partition coeffi cient (n-octanol/water) of these complexes was measured.

U2 - 10.1134/s1066362224040143

DO - 10.1134/s1066362224040143

M3 - Article

VL - 66

SP - 521

EP - 529

JO - Radiochemistry

JF - Radiochemistry

SN - 1066-3622

IS - 4

ER -

ID: 124716501