Research output: Contribution to journal › Article › peer-review
2‐(1,2,4‐Oxadiazol‐5‐yl)aniline as a New Scaffold for Blue Luminescent Materials. / Байков, Сергей Валентинович; Тарасенко, Марина; Котлярова, В.; Шетнев, А.А.; Зеленков, Лев Евгеньевич; Боярская, Ирина Алексеевна; Боярский, Вадим Павлович.
In: ChemistrySelect, Vol. 7, No. 29, e202201201, 01.08.2022.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - 2‐(1,2,4‐Oxadiazol‐5‐yl)aniline as a New Scaffold for Blue Luminescent Materials
AU - Байков, Сергей Валентинович
AU - Тарасенко, Марина
AU - Котлярова, В.
AU - Шетнев, А.А.
AU - Зеленков, Лев Евгеньевич
AU - Боярская, Ирина Алексеевна
AU - Боярский, Вадим Павлович
N1 - Publisher Copyright: © 2022 Wiley-VCH GmbH.
PY - 2022/8/1
Y1 - 2022/8/1
N2 - Condensation of amidoximes 1 with isatoic anhydrides 2 or esters 3 in NaOH/DMSO medium afforded to substituted 1,2,4-oxadiazolyl anilines. The compounds synthesized can exhibit luminescence, the presence and efficiency of which depends on the position of the amino group in these aminophenyl 1,2,4-oxadiazol derivatives. The best luminophores are 2-(orthoaminophenyl) 1,2,4-oxadiazoles. More than 20 examples of the new organic luminophores were synthesized and studied. The effect of the luminophore structure on the emission band and on the quantum yield indicates that a luminescent scaffold has been obtained.
AB - Condensation of amidoximes 1 with isatoic anhydrides 2 or esters 3 in NaOH/DMSO medium afforded to substituted 1,2,4-oxadiazolyl anilines. The compounds synthesized can exhibit luminescence, the presence and efficiency of which depends on the position of the amino group in these aminophenyl 1,2,4-oxadiazol derivatives. The best luminophores are 2-(orthoaminophenyl) 1,2,4-oxadiazoles. More than 20 examples of the new organic luminophores were synthesized and studied. The effect of the luminophore structure on the emission band and on the quantum yield indicates that a luminescent scaffold has been obtained.
KW - 1,2,4-Oxadiazoles
KW - Amidoximes
KW - Isatoic anhydride
KW - Luminescent scaffold
KW - Solvatochromism
UR - https://onlinelibrary.wiley.com/doi/10.1002/slct.202201201
UR - https://www.mendeley.com/catalogue/1957b2fb-14b9-37ca-8fda-ea65d60baf4f/
UR - http://www.scopus.com/inward/record.url?scp=85135847057&partnerID=8YFLogxK
U2 - 10.1002/slct.202201201
DO - 10.1002/slct.202201201
M3 - Article
VL - 7
JO - ChemistrySelect
JF - ChemistrySelect
SN - 2365-6549
IS - 29
M1 - e202201201
ER -
ID: 97531745