Abstract: 2+1 tricarbonyl complexes [Re(CO)3(N^N)CNCH2COOEt]X, where N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen) and X = Cl or ClO4, were prepared and isolated by two procedures. The intermediate tricarbonyl complexes [Re(CO)3(N^N)X] (where X = Cl or ClO4) were also isolated. The composition and molecular structure of these complexes were determined by single crystal X-ray diffraction analysis. The complexes have fac-tricarbonyl structure with bidentate coordination of bipy and phen. The complexes were characterized by PL, IR, UV-Vis, and 1H NMR spectroscopy and by elemental analysis.

Original languageEnglish
Pages (from-to)69-78
Number of pages10
JournalRussian Journal of General Chemistry
Issue number1
StatePublished - Jan 2022

    Research areas

  • bipyridine, ethyl isocyanoacetate, phenanthroline, rhenium, single crystal X-ray diffraction, spectroscopy, tricarbonyl complexes

    Scopus subject areas

  • Chemistry(all)

ID: 98952920