Research output: Contribution to journal › Article › peer-review
Гетеролептические галогенидные комплексы Zn(II) с иодзамещенными бензонитрилами: особенности галогенной связи в твердом теле. / Vershinin, M. A.; Novikov, A. S.; Sokolov, M. N.; Adonin, S. A.
In: КООРДИНАЦИОННАЯ ХИМИЯ, Vol. 50, No. 1, 01.08.2024, p. 3-10.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Гетеролептические галогенидные комплексы Zn(II) с иодзамещенными бензонитрилами: особенности галогенной связи в твердом теле
AU - Vershinin, M. A.
AU - Novikov, A. S.
AU - Sokolov, M. N.
AU - Adonin, S. A.
PY - 2024/8/1
Y1 - 2024/8/1
N2 - The reactions of zinc(II) bromide with 3- and 4-iodobenzonitriles (3-I-BzCN and 4-I-Bz-CN) afford heteroligand complexes [L2ZnBr2] (L = 3-I-BzCN (I) and 4-I-BzCN (II)), whose structures are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2253175 (I) and 2253176 (II)). Both crystal structures contain halogen bonds I···Br linking the [ZnBr2L2] fragments into supramolecular layers (I) or chains (II). The energies of these noncovalent interactions are estimated by quantum-chemical calculations.
AB - The reactions of zinc(II) bromide with 3- and 4-iodobenzonitriles (3-I-BzCN and 4-I-Bz-CN) afford heteroligand complexes [L2ZnBr2] (L = 3-I-BzCN (I) and 4-I-BzCN (II)), whose structures are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2253175 (I) and 2253176 (II)). Both crystal structures contain halogen bonds I···Br linking the [ZnBr2L2] fragments into supramolecular layers (I) or chains (II). The energies of these noncovalent interactions are estimated by quantum-chemical calculations.
UR - https://www.mendeley.com/catalogue/01ec1062-944c-3d2e-857d-3df445400e29/
U2 - 10.31857/s0132344x24010011
DO - 10.31857/s0132344x24010011
M3 - статья
VL - 50
SP - 3
EP - 10
JO - КООРДИНАЦИОННАЯ ХИМИЯ
JF - КООРДИНАЦИОННАЯ ХИМИЯ
SN - 0132-344X
IS - 1
ER -
ID: 124401076