The sequences of Fermi resonances vs~2vb in the IR spectrum of a solution of fluoroform (CHF3) in liquefied krypton are investigated. Here vs is the CH stretching vibration, vb is the bending vibration. It is shown that for a correct description of resonance multiplets (polyads) at a high degree of vibrational excitation, it is necessary to use an extended set of spectroscopic parameters. In particular, it is necessary to take into account the dependence of the anharmonic interaction constant asbb on the vibrational quantum numbers. The conclusions are generalized for the arbitrary case of the CH-chromophore CHX3.
Translated title of the contributionFTIR Cryospectroscopic study of Fermi resonance polyads vs=2vb in CHF3
Original languageRussian
Pages (from-to)1019-1026
JournalOPTICS AND SPECTROSCOPY
Volume129
Issue number8
StatePublished - 1 Aug 2021

    Research areas

  • FERMI RESONANCE, anharmonicity, CH-CHROMOPHORE, FLUOROFORM, CHF3

ID: 90255559