TY - JOUR

T1 - Young's and shear moduli of Fe3+-doped chrysotile nanoscrolls probed by atomic force microscopy

AU - Krasilin, A.A.

AU - Khalisov, M.M.

AU - Kozhevina, A.V.

AU - Kozlov, D.A.

AU - Danilov, D.V.

AU - Loshachenko, A.S.

AU - Enyashin, A.N.

AU - Ankudinov, A.V.

N1 - Export Date: 4 March 2024 Адрес для корреспонденции: Krasilin, A.A.; Ioffe Institute, 26 Politekhnicheskaya st., Russian Federation; эл. почта: ikrasilin@mail.ioffe.ru Сведения о финансировании: Russian Science Foundation, RSF, 19–13-00151 Текст о финансировании 1: The research was partially supported by the Russian Science Foundation grant 19–13-00151, https://rscf.ru/en/project/19–13-00151/ . The investigation of the morphology by means of electron microscopy was carried out at the IRC for Nanotechnology of the Science Park of St. Petersburg State University within the framework of project No. АААА-А19–119091190094. Additional STEM studies were performed using the equipment of the JRC PMR IGIC RAS. 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PY - 2024/3/1

Y1 - 2024/3/1

N2 - Here, we investigate an influence of Fe3+ content on the mechanical behavior of Mg3Si2O5(OH)4 synthetic phyllosilicate nanoscrolls with chrysotile structure during the bending tests carried out by atomic force microscopy. The developed approach to the microscopy data treatment allowed us to consider fixing conditions, elasticity of the foundation, and shear strain contributions to the observed Young's modulus value. Doping by 6 at% of Fe3+ decreased the Young's modulus from 238 down to 150 GPa. The applied density-functional theory calculations confirmed the same trend for the most energy preferable types of Mg2+ and Si4+ substitutons by Fe3+. Despite major part of the experimental data has been satisfactory explained within the shear strain contribution assumption, doping by Fe3+ gives rise to nanoscrolls with anomalous Young's modulus value (600 ± 200 GPa). Potential reasons of the effect are considered. © 2024 Elsevier Ltd

AB - Here, we investigate an influence of Fe3+ content on the mechanical behavior of Mg3Si2O5(OH)4 synthetic phyllosilicate nanoscrolls with chrysotile structure during the bending tests carried out by atomic force microscopy. The developed approach to the microscopy data treatment allowed us to consider fixing conditions, elasticity of the foundation, and shear strain contributions to the observed Young's modulus value. Doping by 6 at% of Fe3+ decreased the Young's modulus from 238 down to 150 GPa. The applied density-functional theory calculations confirmed the same trend for the most energy preferable types of Mg2+ and Si4+ substitutons by Fe3+. Despite major part of the experimental data has been satisfactory explained within the shear strain contribution assumption, doping by Fe3+ gives rise to nanoscrolls with anomalous Young's modulus value (600 ± 200 GPa). Potential reasons of the effect are considered. © 2024 Elsevier Ltd

KW - Bending test

KW - Density-functional theory

KW - Fixing conditions

KW - Hydrothermal synthesis

KW - Mechanical properties

KW - Phyllosilicate

KW - Atomic force microscopy

KW - Bending tests

KW - Density (specific gravity)

KW - Elastic moduli

KW - Hydrogen bonds

KW - Magnesium compounds

KW - Shear strain

KW - Silicon

KW - Silicon compounds

KW - Atomic-force-microscopy

KW - Condition

KW - Density-functional-theory

KW - Fe 3+

KW - Fixing condition

KW - Mechanical behavior

KW - Modulus values

KW - Nanoscrolls

KW - Young modulus

KW - Density functional theory

UR - https://www.mendeley.com/catalogue/12ff2efa-71cb-34c8-841c-d1e797372c00/

U2 - 10.1016/j.mtcomm.2024.108358

DO - 10.1016/j.mtcomm.2024.108358

M3 - статья

VL - 38

JO - Materials Today Communications

JF - Materials Today Communications

SN - 2352-4928

M1 - 108358

ER -