TY - JOUR

T1 - Water-stable [Ni(salen)]-type electrode material based on phenylazosubstituted salicylic aldehyde imine ligand

AU - Vereschagin, Anatoly A.

AU - Sizov, Vladimir V.

AU - Vlasov, Petr S.

AU - Alekseeva, Elena V.

AU - Konev, Alexander S.

AU - Levin, Oleg V.

PY - 2017

Y1 - 2017

N2 - A novel electrode material was prepared by electrochemical oxidation of [4,4′-phenylazo-2,2′-(ethylenediimino-κ2N-methyl)diphenolate-κ2O]nickel, a [Ni(ii)(salen)]-type complex, in chlorinated solvent. The chemical structure of the material was explored by FTIR, NMR and XPS techniques to determine the main components of the material and the nature of the linkage between them. The morphology of the material films was explored by SEM analysis. The electrochemical properties of the new material were studied by a set of voltammetric methods and an unusual stability of the material in aqueous medium was observed.

AB - A novel electrode material was prepared by electrochemical oxidation of [4,4′-phenylazo-2,2′-(ethylenediimino-κ2N-methyl)diphenolate-κ2O]nickel, a [Ni(ii)(salen)]-type complex, in chlorinated solvent. The chemical structure of the material was explored by FTIR, NMR and XPS techniques to determine the main components of the material and the nature of the linkage between them. The morphology of the material films was explored by SEM analysis. The electrochemical properties of the new material were studied by a set of voltammetric methods and an unusual stability of the material in aqueous medium was observed.

UR - http://www.scopus.com/inward/record.url?scp=85034626239&partnerID=8YFLogxK

U2 - 10.1039/c7nj03526h

DO - 10.1039/c7nj03526h

M3 - Article

AN - SCOPUS:85034626239

VL - 41

SP - 13918

EP - 13928

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 22

ER -