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Water Hardness Electrodes with Ionophores Containing Oxy- and Ester-Groups. / Левин, Михаил Борисович; Хрипун, Галина Анатольевна; Корнеев, Сергей Михайлович; Михельсон, Константин Николаевич.

в: Russian Journal of Electrochemistry, Том 54, № 4, 01.04.2018, стр. 391-399.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Левин, МБ, Хрипун, ГА, Корнеев, СМ & Михельсон, КН 2018, 'Water Hardness Electrodes with Ionophores Containing Oxy- and Ester-Groups', Russian Journal of Electrochemistry, Том. 54, № 4, стр. 391-399. https://doi.org/10.1134/S1023193518040055

APA

Левин, М. Б., Хрипун, Г. А., Корнеев, С. М., & Михельсон, К. Н. (2018). Water Hardness Electrodes with Ionophores Containing Oxy- and Ester-Groups. Russian Journal of Electrochemistry, 54(4), 391-399. https://doi.org/10.1134/S1023193518040055

Vancouver

Левин МБ, Хрипун ГА, Корнеев СМ, Михельсон КН. Water Hardness Electrodes with Ionophores Containing Oxy- and Ester-Groups. Russian Journal of Electrochemistry. 2018 Апр. 1;54(4):391-399. https://doi.org/10.1134/S1023193518040055

Author

Левин, Михаил Борисович ; Хрипун, Галина Анатольевна ; Корнеев, Сергей Михайлович ; Михельсон, Константин Николаевич. / Water Hardness Electrodes with Ionophores Containing Oxy- and Ester-Groups. в: Russian Journal of Electrochemistry. 2018 ; Том 54, № 4. стр. 391-399.

BibTeX

@article{11c3824fd8024907896a8259153cf361,
title = "Water Hardness Electrodes with Ionophores Containing Oxy- and Ester-Groups",
abstract = "Lipophilic compounds combining oxy- and ester-groups are synthesized and studied as neutral ionophores in plasticized PVC membranes for the development of novel water hardness ion-selective electrodes. Electrodes based on the ionophores studied showed a higher selectivity to calcium over magnesium ions. However, for electrodes based on hexadecyl-4-hydroxybutanoate or decyloxybutanol this preference turned to be rather low: logK CaMg=–(0.5–0.7). Electrodes with membranes containing hexadecyl-4- hydroxybutanoate, 0.3 M as a neutral ionophore and bis[4-(1,1,3,3-tetramethylbutyl)phenyl]phosphate, 0.01 M as a charged ionophore, in combination with Ca 2+-selective electrode based on ETH 1001 as ionophore, proved to be suitable for measurements of water hardness, also for the measurement of Mg 2+ ion content in artificial aquarium fish-breeding water samples and in samples modeling electrolyte composition of blood serum. ",
keywords = "ion-selective electrodes, ionophores with oxy- and ester-groups, water hardness",
author = "Левин, {Михаил Борисович} and Хрипун, {Галина Анатольевна} and Корнеев, {Сергей Михайлович} and Михельсон, {Константин Николаевич}",
note = "Funding Information: ACKNOWLEDGMENTS This study was supported by the Russian Foundation for Basic Research, grant 15-03-04514.",
year = "2018",
month = apr,
day = "1",
doi = "10.1134/S1023193518040055",
language = "English",
volume = "54",
pages = "391--399",
journal = "Russian Journal of Electrochemistry",
issn = "1023-1935",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Water Hardness Electrodes with Ionophores Containing Oxy- and Ester-Groups

AU - Левин, Михаил Борисович

AU - Хрипун, Галина Анатольевна

AU - Корнеев, Сергей Михайлович

AU - Михельсон, Константин Николаевич

N1 - Funding Information: ACKNOWLEDGMENTS This study was supported by the Russian Foundation for Basic Research, grant 15-03-04514.

PY - 2018/4/1

Y1 - 2018/4/1

N2 - Lipophilic compounds combining oxy- and ester-groups are synthesized and studied as neutral ionophores in plasticized PVC membranes for the development of novel water hardness ion-selective electrodes. Electrodes based on the ionophores studied showed a higher selectivity to calcium over magnesium ions. However, for electrodes based on hexadecyl-4-hydroxybutanoate or decyloxybutanol this preference turned to be rather low: logK CaMg=–(0.5–0.7). Electrodes with membranes containing hexadecyl-4- hydroxybutanoate, 0.3 M as a neutral ionophore and bis[4-(1,1,3,3-tetramethylbutyl)phenyl]phosphate, 0.01 M as a charged ionophore, in combination with Ca 2+-selective electrode based on ETH 1001 as ionophore, proved to be suitable for measurements of water hardness, also for the measurement of Mg 2+ ion content in artificial aquarium fish-breeding water samples and in samples modeling electrolyte composition of blood serum.

AB - Lipophilic compounds combining oxy- and ester-groups are synthesized and studied as neutral ionophores in plasticized PVC membranes for the development of novel water hardness ion-selective electrodes. Electrodes based on the ionophores studied showed a higher selectivity to calcium over magnesium ions. However, for electrodes based on hexadecyl-4-hydroxybutanoate or decyloxybutanol this preference turned to be rather low: logK CaMg=–(0.5–0.7). Electrodes with membranes containing hexadecyl-4- hydroxybutanoate, 0.3 M as a neutral ionophore and bis[4-(1,1,3,3-tetramethylbutyl)phenyl]phosphate, 0.01 M as a charged ionophore, in combination with Ca 2+-selective electrode based on ETH 1001 as ionophore, proved to be suitable for measurements of water hardness, also for the measurement of Mg 2+ ion content in artificial aquarium fish-breeding water samples and in samples modeling electrolyte composition of blood serum.

KW - ion-selective electrodes

KW - ionophores with oxy- and ester-groups

KW - water hardness

UR - http://www.scopus.com/inward/record.url?scp=85046668811&partnerID=8YFLogxK

U2 - 10.1134/S1023193518040055

DO - 10.1134/S1023193518040055

M3 - Article

VL - 54

SP - 391

EP - 399

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 4

ER -

ID: 24072767