Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Voltammetry with a fluoride-selective electrode with solid-phase reference system. / Turaeva, M. S.; Kot, S. A.; Glumov, O. V.; Murin, I. V.
в: Russian Journal of Applied Chemistry, Том 74, № 4, 01.01.2001, стр. 596-602.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Voltammetry with a fluoride-selective electrode with solid-phase reference system
AU - Turaeva, M. S.
AU - Kot, S. A.
AU - Glumov, O. V.
AU - Murin, I. V.
PY - 2001/1/1
Y1 - 2001/1/1
N2 - Experimental results obtained in a study of the voltammetric response of an all-solid fluoride-selective electrode based on LaF3 (Eu2+ 0.8 mol %), LaF3 (Sr2+ 5 mol %) and CeF3 (Sr2+ 5 mol %) single crystals brought in contact with Ag, Bi, and Sn metal samples are presented. The method of cathodic inversion voltammetry was applied to study the reduction of La3+ and Ce3+ - cations from the rigid sublattice of solid electrolytes, which determines the threshold of the electrochemical stability of a membrane. Anodic inversion voltammetry was used to investigate the characteristics of solid-phase generation of metal fluorides at the interface between the fluoride-selective electrode and metals.
AB - Experimental results obtained in a study of the voltammetric response of an all-solid fluoride-selective electrode based on LaF3 (Eu2+ 0.8 mol %), LaF3 (Sr2+ 5 mol %) and CeF3 (Sr2+ 5 mol %) single crystals brought in contact with Ag, Bi, and Sn metal samples are presented. The method of cathodic inversion voltammetry was applied to study the reduction of La3+ and Ce3+ - cations from the rigid sublattice of solid electrolytes, which determines the threshold of the electrochemical stability of a membrane. Anodic inversion voltammetry was used to investigate the characteristics of solid-phase generation of metal fluorides at the interface between the fluoride-selective electrode and metals.
UR - http://www.scopus.com/inward/record.url?scp=24944537669&partnerID=8YFLogxK
U2 - 10.1023/A:1012758515388
DO - 10.1023/A:1012758515388
M3 - Article
AN - SCOPUS:24944537669
VL - 74
SP - 596
EP - 602
JO - Russian Journal of Applied Chemistry
JF - Russian Journal of Applied Chemistry
SN - 1070-4272
IS - 4
ER -
ID: 52786387