Standard

Versatile reactivity of bridged pentelidene complexes toward secondary and tertiary phosphines. / Stubenhofer, M.; Kuntz, C.; Bodensteiner, M.; Timoshkin, A.Y.; Scheer, M.

в: Organometallics, Том 32, № 12, 2013, стр. 3521-3528.

Результаты исследований: Научные публикации в периодических изданиях › статья

Harvard

Stubenhofer, M, Kuntz, C, Bodensteiner, M, Timoshkin, AY & Scheer, M 2013, 'Versatile reactivity of bridged pentelidene complexes toward secondary and tertiary phosphines', Organometallics, Том. 32, № 12, стр. 3521-3528. https://doi.org/10.1021/om400357y

APA

Stubenhofer, M., Kuntz, C., Bodensteiner, M., Timoshkin, A. Y., & Scheer, M. (2013). Versatile reactivity of bridged pentelidene complexes toward secondary and tertiary phosphines. Organometallics, 32(12), 3521-3528. https://doi.org/10.1021/om400357y

Vancouver

Stubenhofer M, Kuntz C, Bodensteiner M, Timoshkin AY, Scheer M. Versatile reactivity of bridged pentelidene complexes toward secondary and tertiary phosphines. Organometallics. 2013;32(12):3521-3528. https://doi.org/10.1021/om400357y

Author

Stubenhofer, M. ; Kuntz, C. ; Bodensteiner, M. ; Timoshkin, A.Y. ; Scheer, M. / Versatile reactivity of bridged pentelidene complexes toward secondary and tertiary phosphines. в: Organometallics. 2013 ; Том 32, № 12. стр. 3521-3528.

BibTeX

@article{4888ffc5e78548e19a68f9dbde0d22b4,
title = "Versatile reactivity of bridged pentelidene complexes toward secondary and tertiary phosphines",
abstract = "The reaction of the phosphinidene complex [Cp*P{W(CO) 5}2] (1a) with secondary and tertiary phosphines, respectively, proceeds via W(CO)5 elimination to form the phosphoranylidene complexes [{W(CO)5}(Cp*)P-P(H) iPr2] (2), [{W(CO)5}(Cp*)P-PMe iPr2] (7), and [{W(CO)5}(Cp*)P-PEt 3] (9). Other novel types of products, the phosphine-coordinated bridged parent phosphinidene complexes [{W(CO)5}2(H)P- PMeiPr2] (6a) and [{W(CO)5}2(H)P- PEt3] (8a), are obtained by elimination of 1,2,3,4- tetramethylfulvene. The latter reaction path is predominantly found for the arsinidene complex [Cp*As{W(CO)5}2] (1b) to yield [{W(CO)5}2(H)As-PHiPr2] (4) upon reaction with HPiPr2 and, with tertiary phosphines, the products [{W(CO)5}2(H)As-PMeiPr2] (6b) and [{W(CO)5}2(H)As-PEt3] (8b). If a secondary phosphine coordinates to a bridged parent pentelidene complex, Cp*H elimination occurs to form either HP[PiPr 2{W(CO)5}]2 (3) or the phosphine-substituted diarsene complex W(CO)5[AsPiPr2{W(CO) 5}]2 (5). Each of the new products has been cha",
author = "M. Stubenhofer and C. Kuntz and M. Bodensteiner and A.Y. Timoshkin and M. Scheer",
year = "2013",
doi = "10.1021/om400357y",
language = "English",
volume = "32",
pages = "3521--3528",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "12",

}

RIS

TY - JOUR

T1 - Versatile reactivity of bridged pentelidene complexes toward secondary and tertiary phosphines

AU - Stubenhofer, M.

AU - Kuntz, C.

AU - Bodensteiner, M.

AU - Timoshkin, A.Y.

AU - Scheer, M.

PY - 2013

Y1 - 2013

N2 - The reaction of the phosphinidene complex [Cp*P{W(CO) 5}2] (1a) with secondary and tertiary phosphines, respectively, proceeds via W(CO)5 elimination to form the phosphoranylidene complexes [{W(CO)5}(Cp*)P-P(H) iPr2] (2), [{W(CO)5}(Cp*)P-PMe iPr2] (7), and [{W(CO)5}(Cp*)P-PEt 3] (9). Other novel types of products, the phosphine-coordinated bridged parent phosphinidene complexes [{W(CO)5}2(H)P- PMeiPr2] (6a) and [{W(CO)5}2(H)P- PEt3] (8a), are obtained by elimination of 1,2,3,4- tetramethylfulvene. The latter reaction path is predominantly found for the arsinidene complex [Cp*As{W(CO)5}2] (1b) to yield [{W(CO)5}2(H)As-PHiPr2] (4) upon reaction with HPiPr2 and, with tertiary phosphines, the products [{W(CO)5}2(H)As-PMeiPr2] (6b) and [{W(CO)5}2(H)As-PEt3] (8b). If a secondary phosphine coordinates to a bridged parent pentelidene complex, Cp*H elimination occurs to form either HP[PiPr 2{W(CO)5}]2 (3) or the phosphine-substituted diarsene complex W(CO)5[AsPiPr2{W(CO) 5}]2 (5). Each of the new products has been cha

AB - The reaction of the phosphinidene complex [Cp*P{W(CO) 5}2] (1a) with secondary and tertiary phosphines, respectively, proceeds via W(CO)5 elimination to form the phosphoranylidene complexes [{W(CO)5}(Cp*)P-P(H) iPr2] (2), [{W(CO)5}(Cp*)P-PMe iPr2] (7), and [{W(CO)5}(Cp*)P-PEt 3] (9). Other novel types of products, the phosphine-coordinated bridged parent phosphinidene complexes [{W(CO)5}2(H)P- PMeiPr2] (6a) and [{W(CO)5}2(H)P- PEt3] (8a), are obtained by elimination of 1,2,3,4- tetramethylfulvene. The latter reaction path is predominantly found for the arsinidene complex [Cp*As{W(CO)5}2] (1b) to yield [{W(CO)5}2(H)As-PHiPr2] (4) upon reaction with HPiPr2 and, with tertiary phosphines, the products [{W(CO)5}2(H)As-PMeiPr2] (6b) and [{W(CO)5}2(H)As-PEt3] (8b). If a secondary phosphine coordinates to a bridged parent pentelidene complex, Cp*H elimination occurs to form either HP[PiPr 2{W(CO)5}]2 (3) or the phosphine-substituted diarsene complex W(CO)5[AsPiPr2{W(CO) 5}]2 (5). Each of the new products has been cha

U2 - 10.1021/om400357y

DO - 10.1021/om400357y

M3 - Article

VL - 32

SP - 3521

EP - 3528

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 12

ER -

ID: 5644602