Standard

Variable-temperature infrared spectroscopy : An access to adsorption thermodynamics of weakly interacting systems. / Otero Areán, C.; Manoilova, O. V.; Turnes Palomino, G.; Rodríguez Delgado, M.; Tsyganenko, A. A.; Bonelli, B.; Garrone, E.

в: Physical Chemistry Chemical Physics, Том 4, № 23, 01.01.2002, стр. 5713-5715.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Otero Areán, C, Manoilova, OV, Turnes Palomino, G, Rodríguez Delgado, M, Tsyganenko, AA, Bonelli, B & Garrone, E 2002, 'Variable-temperature infrared spectroscopy: An access to adsorption thermodynamics of weakly interacting systems', Physical Chemistry Chemical Physics, Том. 4, № 23, стр. 5713-5715. https://doi.org/10.1039/b209299a

APA

Otero Areán, C., Manoilova, O. V., Turnes Palomino, G., Rodríguez Delgado, M., Tsyganenko, A. A., Bonelli, B., & Garrone, E. (2002). Variable-temperature infrared spectroscopy: An access to adsorption thermodynamics of weakly interacting systems. Physical Chemistry Chemical Physics, 4(23), 5713-5715. https://doi.org/10.1039/b209299a

Vancouver

Otero Areán C, Manoilova OV, Turnes Palomino G, Rodríguez Delgado M, Tsyganenko AA, Bonelli B и пр. Variable-temperature infrared spectroscopy: An access to adsorption thermodynamics of weakly interacting systems. Physical Chemistry Chemical Physics. 2002 Янв. 1;4(23):5713-5715. https://doi.org/10.1039/b209299a

Author

Otero Areán, C. ; Manoilova, O. V. ; Turnes Palomino, G. ; Rodríguez Delgado, M. ; Tsyganenko, A. A. ; Bonelli, B. ; Garrone, E. / Variable-temperature infrared spectroscopy : An access to adsorption thermodynamics of weakly interacting systems. в: Physical Chemistry Chemical Physics. 2002 ; Том 4, № 23. стр. 5713-5715.

BibTeX

@article{826d2a01cfad477696d69756a8b481e6,
title = "Variable-temperature infrared spectroscopy: An access to adsorption thermodynamics of weakly interacting systems",
abstract = "Variable-temperature FTIR spectroscopy, with the simultaneous measurement of temperature and equilibrium pressure, is shown to be a convenient method for the thermodynamic study of adsorbent-adsorbate systems. When weak interactions are concerned, the technique presents favourable features, as compared to classical microcalorimetric measurements. This recently developed spectroscopic method is demonstrated by studying the adsorption of dinitrogen on the protonic zeolite H-ZSM-5, a system for which the availability of microcalorimetric measurements affords a direct check of the new method. The relevant thermodynamic quantities determined for this system are ΔH° = -19.7(±0.5) kJ mol-1 and ΔS° = -125(±5) J mol-1 K-1; the standard adsorption enthalpy compares favourably with the microcalorimetrically determined value of about 19 kJ mol-1.",
author = "{Otero Are{\'a}n}, C. and Manoilova, {O. V.} and {Turnes Palomino}, G. and {Rodr{\'i}guez Delgado}, M. and Tsyganenko, {A. A.} and B. Bonelli and E. Garrone",
year = "2002",
month = jan,
day = "1",
doi = "10.1039/b209299a",
language = "English",
volume = "4",
pages = "5713--5715",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",
number = "23",

}

RIS

TY - JOUR

T1 - Variable-temperature infrared spectroscopy

T2 - An access to adsorption thermodynamics of weakly interacting systems

AU - Otero Areán, C.

AU - Manoilova, O. V.

AU - Turnes Palomino, G.

AU - Rodríguez Delgado, M.

AU - Tsyganenko, A. A.

AU - Bonelli, B.

AU - Garrone, E.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - Variable-temperature FTIR spectroscopy, with the simultaneous measurement of temperature and equilibrium pressure, is shown to be a convenient method for the thermodynamic study of adsorbent-adsorbate systems. When weak interactions are concerned, the technique presents favourable features, as compared to classical microcalorimetric measurements. This recently developed spectroscopic method is demonstrated by studying the adsorption of dinitrogen on the protonic zeolite H-ZSM-5, a system for which the availability of microcalorimetric measurements affords a direct check of the new method. The relevant thermodynamic quantities determined for this system are ΔH° = -19.7(±0.5) kJ mol-1 and ΔS° = -125(±5) J mol-1 K-1; the standard adsorption enthalpy compares favourably with the microcalorimetrically determined value of about 19 kJ mol-1.

AB - Variable-temperature FTIR spectroscopy, with the simultaneous measurement of temperature and equilibrium pressure, is shown to be a convenient method for the thermodynamic study of adsorbent-adsorbate systems. When weak interactions are concerned, the technique presents favourable features, as compared to classical microcalorimetric measurements. This recently developed spectroscopic method is demonstrated by studying the adsorption of dinitrogen on the protonic zeolite H-ZSM-5, a system for which the availability of microcalorimetric measurements affords a direct check of the new method. The relevant thermodynamic quantities determined for this system are ΔH° = -19.7(±0.5) kJ mol-1 and ΔS° = -125(±5) J mol-1 K-1; the standard adsorption enthalpy compares favourably with the microcalorimetrically determined value of about 19 kJ mol-1.

UR - http://www.scopus.com/inward/record.url?scp=0036433715&partnerID=8YFLogxK

U2 - 10.1039/b209299a

DO - 10.1039/b209299a

M3 - Article

AN - SCOPUS:0036433715

VL - 4

SP - 5713

EP - 5715

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 23

ER -

ID: 41680948