We have studied thermodynamics of vapor nucleation on a spherical wettable dielectric nanoparticle carrying a discrete electric charge located at a certain distance from the particle center. New general equations for the chemical potential of a condensate molecule in the droplet around the particle, the work of the droplet formation and the droplet shape as functions of the effective radius of condensate film, and the value of an electric charge and its location with respect to the particle center have been derived analytically. These equations take into account both the effects of the non-central electric field and the disjoining pressure in the thin liquid film forming the droplet. Under the assumption of small distortion of the droplet shape in the axisymmetric electric field of non-central discrete charge from the spherical one, these equations have been simultaneously solved analytically. The obtained explicit formulas for the condensate chemical potential, the work of droplet formation, and the droplet
Язык оригиналаанглийский
Страницы (с-по)194708_1-12
ЖурналJournal of Chemical Physics
Том138
Номер выпуска19
DOI
СостояниеОпубликовано - 2013

ID: 7371066